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The Pauli exclusion principle is a rule of the quantum world that forbids two particles from being in the same state at the same time. Imagine a theater where each seat has a unique row and seat number. Fermion spectators (such as electrons) cannot sit in the same seat together: each needs its own. Thanks to this, atoms do not collapse, and chemical elements differ from each other.

How it works

The principle works wherever there are fermions: in atoms, metals, white dwarf stars. In an atom, electrons fill orbitals sequentially, and this defines the Periodic Table. In metals, thanks to the Pauli principle, electrons are distributed by energy, creating degenerate gas pressure that resists the compression of white dwarfs.

💡 If it weren't for the Pauli principle, all electrons in an atom would gather in the lowest orbital, and then there would be no chemistry, no life — all atoms would be like inert gases.
\Psi(\dots, x_i, \dots, x_j, \dots) = -\Psi(\dots, x_j, \dots, x_i, \dots)
Ψ is the wave function of the system, x_i are the coordinates and spin of the i-th particle.
Links in the knowledge graph 1
Discovered by
Wolfgang PauliErwin SchrödingerPaul Dirac
Related concepts
angular momentumsuperconductivity
Related laws
Schrödinger equationDirac equation

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