A crystalline film thinner than a human hair lies on a rigid substrate like a carpet nailed to the floor. The substrate prevents the film from freely changing shape when heated: it expands and contracts stiffly, losing sensitivity. In the new work, the film was separated from the substrate by dissolving an intermediate layer in water. The free-standing film, transferred onto silicon, became four times better at converting heat into an electrical signal at room temperature.
At 60°C, sensitivity increased 34-fold. Microscopy revealed that in the free-standing film, thermal vibrations more easily rearrange internal regions with different charge orientations, as if the carpet can now flex freely rather than just ruffle slightly. Such a film detects infrared heat without the bulky cooling required by conventional detectors and can scavenge low-temperature waste heat from electronics.
The pyroelectric effect in barium titanate has been known since the 1940s, but only the free-standing film has brought sensitivity close to the theoretical limit.
In the series 'The Expanse,' ships harvest energy from reactor heat — free-standing pyroelectric films make such harvesting possible right now.