A classic piezoelectric crystal used as a model material for studying the photogalvanic effect.Barium titanate (BaTiO₃) is a crystalline oxide that belongs to a class of materials called ferroelectrics. In its ferroelectric phase, it possesses a spontaneous electric polarization that can be reversed by an applied electric field. It is also piezoelectric, meaning mechanical stress generates an electric voltage, and vice versa. Because of these properties, barium titanate is a model material for studying the photogalvanic effect — the generation of a steady electric current in a crystal when illuminated by light, without any external voltage. This effect arises from the asymmetric crystal structure, which allows light to drive charge carriers in a preferred direction.
Barium titanate was discovered during World War II, independently in the United States, the Soviet Union, and Japan, around 1943–1944. Its ferroelectric properties were identified shortly after, making it the first ferroelectric ceramic and a cornerstone of modern electronics.
The photogalvanic effect in barium titanate relies on its non-centrosymmetric crystal structure. When light is absorbed, it excites electrons from the valence band to the conduction band. In a symmetric material, these excited electrons move randomly, producing no net current. But in barium titanate, the lack of inversion symmetry means that the probability of an electron moving in one direction is higher than in the opposite direction. This asymmetry, combined with the material's ferroelectric polarization, creates a net drift of charge carriers, resulting in a measurable photocurrent. The direction and magnitude of this current depend on the light's polarization and the crystal's orientation.
Barium titanate is widely used in multilayer ceramic capacitors, piezoelectric sensors and actuators, and nonlinear optical devices. In research, it serves as a testbed for understanding photovoltaic effects in ferroelectrics, which could lead to more efficient solar cells.
Barium titanate's piezoelectric coefficient is so strong that a thin film of it can generate enough voltage to power micro-electromechanical systems (MEMS) just from mechanical vibrations.




















