A Quantum Duet of Tin and Lithium in a Crystal express

Original: "Identification of the I$$_{10}$$ Donor in ZnO as a Sn--Li Complex with Large Hyperfine Interaction"
arXiv:2603.05615 · 2026-03-05 · CC BY 4.0 · 1 min
A tin–lithium complex in zinc oxide exhibits an unusually strong coupling between electron and nuclear spins.

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Hidden inside a zinc oxide crystal is a quantum duo: a tin atom and a lithium atom sitting side by side. Their bond is so tight that the electron captured by this pair seems to live on the tin, while the lithium merely plays along. This complex was long sought after, but only now has it been deliberately created and identified by its characteristic glow.

The electron here doesn't just orbit the nucleus: its spin is strongly coupled to the tin nucleus's spin. It's like two dancers who always move in sync, and one cannot turn without turning the other.

The strength of this coupling has been precisely measured: 392 megahertz. For comparison, in typical donors in silicon, the coupling is tens of times weaker. Such a strong pair allows very fast manipulation of the nuclear spin — literally within billionths of a second. This means quantum information can be written into the nucleus and read out with light.

Zinc oxide is a wide-bandgap semiconductor, meaning its electrons require a lot of energy to be excited. Therefore, optical transitions here are robust against heating: the complex continues to work at temperatures where conventional donors already 'fall silent'.

This work shows that not only single impurities but also their pairs can serve as building blocks for quantum devices. The tin–lithium complex opens a new direction in the design of quantum defects — with a nuclear spin ready for dialogue with photons.

The hyperfine interaction in this complex is so strong that the transition frequency between spin states is comparable to the frequencies at which microwave ovens operate.

Scientists
Christian DopplerD. B. McLaughlinDidier QuelozMichel MayorR. A. RossiterJames Clerk Maxwell
Concepts
boron lithium niobate lz niobium nitride electron ion collider silicon nitride electron pairs donor star proton