Sulfur in Icy Pockets express

Original: "Ice as a Photochemical Shield: Adsorption Energetics and Spectroscopic Modulation of Interstellar Thiocyanates HCSCN and HCSCCH in TMC-1"
arXiv:2604.17536 · 2026-04-19 · CC BY 4.0 · 1 min
Sulfur-bearing molecules find refuge in ice, but the refuge turns out to be a trap.

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In a cold cloud of gas and dust that astronomers call TMC-1, two sulfur-bearing compounds were recently found: one smells like bitter almonds, the other like rotten eggs. But such a cloud contains less sulfur than it should. Where does it go? It seems to hide in tiny icy pockets on the surface of dust grains.

Space ice is not like a skating rink. It is fluffy, like snow, and full of crevices and hollows. A molecule that lands in a deep hollow sits there firmly, like a key in a lock. To pull it out, you would need to heat the ice to a temperature at which lead melts. But here's the catch: it is precisely in such shelters that the molecule is most vulnerable to ultraviolet starlight.

Starlight can tear a molecule apart, even at minus 260 degrees Celsius.

This creates a paradox: a deep pit protects the molecule from evaporation but makes it a target for light. So sulfur does not gradually escape from the ice into the gas, as expected; instead, it is partially destroyed right in its hiding place. That explains why there is so little of it in the gas.

The same mechanism may work for other substances important for the origin of life. Icy pockets are not just storage: they are places where chemistry takes its own path.

The temperature at which molecules evaporate from icy pockets reaches 4900 degrees — hotter than the surface of the Sun.

Scientists
James JeansMichael FaradayHendrik LorentzEmile ClapeyronClaude-Louis NavierGeorge Gabriel Stokes
Concepts
ice grain molecular formation water ice perovskite solar cell hydrogen cyanide intracluster medium subsurface ocean chlorophyll icecube