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perovskite solar cell

A solar cell using a perovskite-structured compound as the light-absorbing layer.
37 related articles

Description

Perovskite solar cells are a class of photovoltaic devices that use a material with a specific crystal structure — the perovskite structure — as the light-absorbing layer. This structure, named after the mineral perovskite (calcium titanate), allows the material to efficiently absorb sunlight across a broad range of wavelengths. What makes these cells so exciting is their rapid rise in efficiency: in just over a decade, laboratory cells have gone from about 3% to over 25% power conversion efficiency, rivaling established silicon technology.

History

The modern era of perovskite solar cells began in 2009 when Tsutomu Miyasaka and colleagues used a perovskite material as a sensitizer in a dye-sensitized solar cell, achieving 3.8% efficiency. Subsequent work by Nam-Gyu Park, Henry Snaith, and others rapidly improved stability and efficiency, establishing the field.

How it works

The perovskite layer absorbs photons, exciting electrons from the valence band to the conduction band, creating electron-hole pairs. These charges are then extracted by adjacent transport layers — an electron transport layer and a hole transport layer — and collected at electrodes to produce an electric current. The crystal structure's high defect tolerance and long carrier diffusion lengths allow efficient charge collection even in thin films, which is key to their performance.

In practice

Perovskite solar cells are used in research and pilot manufacturing, often in tandem with silicon to boost efficiency beyond single-junction limits, and are being developed for lightweight, flexible, and semi-transparent applications.

Fun fact

The perovskite crystal structure is so versatile that the same family of materials is used in light-emitting diodes, lasers, and even radiation detectors.

Concept graph →

Related articles · 37

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