Why Left- and Right-Handed Molecules Conduct Electricity Differently express

Original: "Chirality-induced spin selectivity without intrinsic spin-orbit coupling: Role of current-induced molecular orbital moment"
arXiv:2606.17865 · 2026-06-16 · CC BY 4.0 · 2 min
The answer lies in tiny magnetic vortices that the current itself creates inside the molecule.

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A spiral staircase sets the rhythm of footsteps: if a stream of people runs up it, their motion inevitably twists. Something similar happens in helical molecules — for example, in DNA or certain proteins. When an electric current is passed through such a molecule, electrons don't just fly straight. They curve around the bends of the molecular chain, and this circular motion generates a tiny magnetic field — a molecular orbital moment.

It is this internal magnetic vortex, as the authors of the new work show, that accounts for a long-standing puzzle in physics — the chirality-induced spin selectivity (CISS) effect. The essence of the effect is simple: a left-handed molecule transmits electrons with one spin direction (intrinsic rotation) better than with the other, and a right-handed molecule does the opposite. Previously, it was thought that the contacts between the molecule and the electrodes were responsible. But experiments hinted that the main 'filter' is the molecule itself.

The magnetic field from the orbital moment is 100–1000 times weaker than the field from the electron itself as a tiny magnet. But that's enough to reliably sort electrons by spin.

The new theory links the direction of this moment to the molecule's chirality: its 'left-handedness' or 'right-handedness.' The moment arises because the electron's path is curved, like a riverbed. This curvature acts on the electron like a magnetic field. As a result, the molecule's resistance changes depending on the magnetization of the contacts — even if the voltage doesn't change sign. The theory doesn't violate fundamental symmetry laws and predicts new effects: for example, current-voltage curves for left- and right-handed molecules can intersect several times.

Thus, a model based on simple geometry and current explains a wide range of phenomena — from magnetoresistance to electrical magnetochiral anisotropy (the dependence of conductivity on the direction of current and magnetic field). The spiral staircase inside the molecule turns out to be the key to controlling spins without external magnets.

The CISS effect is so strong that in some molecules, electron spin polarization can reach nearly 100 percent, like an ideal magnetic filter, but without bulky magnets.

Scientists
Enrico FermiPaul DiracWolfgang PauliErwin SchrödingerPeter HiggsJohannes Kepler
Concepts
spin axis molecular motor chirality magnetic moment spin polarization magnetic textures orbital motion spin