Chaos in a Crystal: How Disorder Awakens Quantum Unpredictability ✎ express

Original: "Many-body quantum chaos in excitonic spectra from first principles"
arXiv:2607.03294 · 2026-07-03 · arXiv non-exclusive · independent analysis · 1 min
In a layered material made of two semiconductors, a transition from order to quantum chaos, driven by lattice defects, has been discovered.

Musicians in an orchestra each play their own part, not hearing the others. In a perfect crystal of tungsten disulfide on graphene, excitons, bound electron-hole pairs, behave the same way: they barely mix due to a hidden symmetry called the valley. The energy levels of such a system resemble notes sorted into separate folders — the chaos is incomplete.

But introduce disorder (say, randomly shifting atoms) and the symmetry disappears. Electronic flat bands emerge, acting as a catalyst: excitons begin to actively mix between valleys. The orchestra turns into a jazz ensemble where every instrument engages in dialogue with the rest. The system becomes fully ergodic: its state covers all available possibilities.

Key result: fluctuations in oscillator strengths, how brightly an exciton absorbs light, follow Porter-Thomas statistics. This is a universal law for quantum chaotic systems. Thus, a direct link emerges between internal chaos and what can be measured in the lab.

The researchers also estimated the Thouless time — the characteristic time over which exciton mixing spans the entire width of the energy band. In a disordered sample, this process happens faster. The layered material becomes a tunable platform for studying quantum chaos: by varying the degree of disorder, one can smoothly transition from regular dynamics to fully chaotic and observe this in optical spectra.

Porter-Thomas statistics, which describes fluctuations in spectral line brightness in chaotic systems, originally appeared in nuclear physics to describe the distribution of neutron resonances.

Scientists
Christian DopplerD. B. McLaughlinDidier QuelozMichel MayorR. A. RossiterJames Clerk Maxwell
Concepts
quantum chaos chaos theory quantum order disorder exciton condensate