The Salt That Dries Out ✛

Original: "A multi-scale study to unravel the dehydration mechanism of hydrated salts"
arXiv:2608.30469v1 · 2026-08-31 · CC BY 4.0 · 1 min
A mirabilite crystal loses water in two stages: first, dry-salt islands appear on the surface, then they grow inward.

A lake drying up during a drought doesn't shrink all at once. First, patches of dry land appear on the surface, they expand and merge, and then the water recedes from the exposed bed. A mirabilite crystal behaves the same way when it loses water: round patches of anhydrous salt appear on it, growing outward, and then they begin to deepen.

Mirabilite is a salt whose crystal contains a lot of water: for every salt particle, there are ten water molecules. When the crystal dries, the water leaves, and another salt, thenardite, remains. Previously, it was thought that drying proceeds uniformly from start to finish, but it turns out there are two distinct stages.

First, small islands of thenardite appear on the surface. They grow sideways, like land patches in a shrinking lake. Then the patches merge, and drying proceeds into the crystal's interior.

After complete drying, the crystal shrinks by about a third and becomes layered, with pores of varying sizes. Air humidity affects the size of thenardite crystals: in dry air they are small, in humid air they are larger. If you compare different salts, some develop round patches upon drying, while others develop cracks. The shape of these patches and cracks can predict in advance how a salt will lose water, which helps in selecting materials for thermal storage.

Mirabilite's energy density (2.4 GJ/m³) is higher than that of lithium-ion batteries (0.72–1.8 GJ/m³), so it is considered a cheap material for seasonal heat storage.

MX \cdot nH_2O (s) + Q \rightleftharpoons MX \cdot mH_2O (s) + (n-m) H_2O (g)
A hydrate with n water molecules, upon heating, releases (n-m) water molecules and transforms into a lower hydrate; upon cooling, the reaction reverses with heat release.
g(\alpha) = \phi \cdot t
The conversion function g(α) depends linearly on time if the chosen model matches the reaction mechanism; φ is the areal growth rate, accounting for the influence of water vapor.
Scientists
Albert EinsteinHans BetheLise MeitnerMargaret BurbidgeFred HoyleRalph Alpher
Concepts
water phase behavior solidification crystallization supercooled water microorganism swimming dynamics dendrite growth liquid material phase transformation demagnetization mass loss rate elasticity deformation sodium battery soil moisture annealing second law of thermodynamics shear electrolyte transport thermalization viscosity