
The process by which a system reaches thermal equilibrium, losing memory of its initial conditions.Thermalization is the process by which a physical system, initially out of equilibrium, evolves toward thermal equilibrium — a state where its macroscopic properties (like temperature) are uniform and it has 'forgotten' its initial conditions. In this state, the system's energy is distributed as evenly as possible among its accessible microscopic states, and the only relevant information left is the total energy, volume, and particle number. This loss of memory is intimately connected to the increase of entropy, as described by the second law of thermodynamics.
The concept of thermal equilibrium dates back to the 19th century with the work of Clausius, Maxwell, and Boltzmann, who established the statistical foundation of thermodynamics. The term 'thermalization' itself emerged with the development of statistical mechanics and kinetic theory.
At the microscopic level, thermalization occurs through interactions: particles collide, exchange energy, and explore the system's phase space. For a large system, this exploration is effectively irreversible because the number of microstates corresponding to equilibrium vastly outnumbers those of any ordered initial state. In quantum systems, thermalization can be understood through the eigenstate thermalization hypothesis (ETH), which states that for a generic interacting system, each individual energy eigenstate already encodes thermal behavior for local observables. However, certain systems (like integrable or many-body localized ones) can resist thermalization, retaining memory of their initial conditions for very long times.
Understanding thermalization is crucial for quantum computing, where decoherence and thermalization limit the coherence time of qubits, and for designing experiments that probe non-equilibrium dynamics, such as the quantum Mpemba effect.
In some quantum systems, a hotter system can cool down faster than a colder one — a quantum version of the Mpemba effect, where the system's initial quantum correlations accelerate its approach to equilibrium.















