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At the outer edge of the zone, where the light barely warms, a 'carbon monoxide collapse' occurs. The cleaner molecules OH stop working, and toxic CO floods the air to hundreds of times Earth's level.
Formaldehyde — a building block for sugars and amino acids — is best 'baked' around hot stars, just before the collapse. Telescopes like James Webb will analyze the light of distant worlds and find places where the recipe for life has almost come together.
On lifeless planets, formaldehyde can be millions of times more abundant than in Earth's air. It has no smell, but without it, you can't assemble sugars and amino acids — the foundation of all living things.