The study of chemical processes occurring in the Earth's atmosphere, including pollutant transformations.Atmospheric chemistry is the study of the chemical composition of planetary atmospheres, the reactions that transform molecules, and the interactions with radiation, aerosols, and surfaces. It explains phenomena from ozone depletion and smog formation on Earth to the photochemical hazes on Titan and the oxidizing environments of Mars. Understanding these processes is crucial for predicting climate change, air quality, and the habitability of other planets.
The field emerged in the mid-20th century with the study of smog in Los Angeles and the discovery of the ozone hole in the 1980s, which linked human-made chlorofluorocarbons to stratospheric depletion.
Atmospheric chemistry involves tracing the sources, sinks, and transformations of trace gases and particles. Key mechanisms include photolysis (molecules broken by sunlight), oxidation reactions (often involving OH radicals), and heterogeneous reactions on aerosol surfaces. Models combine reaction rate constants, transport dynamics, and radiative transfer to simulate how the composition evolves over time.
Atmospheric chemistry informs air quality regulations, climate models, and the design of instruments for monitoring pollutants and greenhouse gases. It also guides the search for biosignatures in exoplanet atmospheres.
The OH radical, a key oxidant in the atmosphere, is so reactive that it survives only about a second before reacting with another molecule, yet it cleanses the atmosphere of many pollutants.















