Plutonium is a metal with attitude. One form shrinks when cooled, another swells. But at room temperature, the alloy behaves strangely: the ruler says one thing, X-rays say another. The ruler shows the sample barely grows, while X-rays see atoms in the crystal lattice moving further apart. Where does the extra volume go?
The answer may lie in the appearance of an invisible phase. Inside the metal, regions form where atoms are packed more tightly than in the regular lattice, but not as tightly as in the most compressed form. These regions are like bubbles in dough, but in reverse: they don't puff up the material: they pull it together. X-rays can't see them because they lack a regular crystal structure: it's an amorphous state, like glass.
So plutonium "heals" itself: dense regions are born and resorbed, compensating for lattice expansion. This explains why length measurements and X-ray data disagreed for so long. Now it's clear: the metal doesn't just expand: it constantly rearranges from within, like a city where foundations are quietly replaced while the streets stay put.
Amorphous metals (metallic glasses) are made by cooling a melt so fast that atoms don't have time to arrange into a crystal. They are stronger than ordinary metals, but when heated, they can "remember" the crystalline state.