law

third law of thermodynamics

The third law of thermodynamics states that the entropy of a perfect crystal approaches zero as the temperature approaches absolute zero.
19 related articles · 2 who worked here

Description

Walther Nernst in 1906 suggested that at absolute zero, the entropy of chemical reactions becomes zero. Later, Max Planck generalized this to the statement that the entropy of any perfect crystal at T=0 is zero. Entropy is a measure of disorder or the number of ways a system can be arranged at the micro-level; at absolute zero, only one, the most ordered, is possible.

History

Walther Nernst, studying chemical reactions at low temperatures, formulated the heat theorem in 1906: the entropy change in a reversible isothermal reaction tends to zero as absolute zero is approached. Max Planck in 1911 gave it a modern statistical interpretation, linking entropy to the number of microstates and postulating that at T=0 this number equals one.

How it works

The law defines the reference point for entropy and allows calculation of absolute entropy values for substances. Applied in cryophysics, in achieving ultra-low temperatures, in superconducting magnet technology. Limits: the law holds for equilibrium systems; glasses and amorphous bodies may have residual entropy at T=0 due to frozen-in disorder.

In practice

This limitation prevents perpetual motion machines from working, explains why something cannot be cooled exactly to −273.15°C, and sets the efficiency limit for refrigerators.

Fun fact

A kettle will never boil by itself, absorbing heat from the room — the third law prevents it, narrowing the path to free energy.

Related articles · 20

Materials2026-09-103 minarXiv:2609.11551
Skyrmion core resolves the Landau paradox
In a perfect crystal of lead titanate, the atoms line up like soldiers on parade: all electric dipoles point the same way. To flip that formation by 180 degrees, old calculations demanded energy comparable to heating the crystal to millions of degrees.
A needle of water: how 10,000 agents made the Navier–Stokes equations blow up
In 1934 Jean Leray proved that the Navier–Stokes equations always have solutions "in a generalized sense". Whether a solution stays smooth or can break down into a singularity he could not tell, and nobody could for ninety years. In 2000 the Clay Institute made the question one of its seven Millennium Prize problems.
Materials2026-08-211 minarXiv:2608.20957express
Methyl Group Heats Up Liquid Crystal to 120 Degrees
In a thin layer of liquid crystal, molecules usually lie like matches in a box — aligned in one direction but randomly oriented: some point up, others down. To make all the matches point the same way, you need a special molecular architecture. Scientists have found a chemical trick that does this almost automatically.
Superconductivity2026-08-181 minarXiv:2608.17777express
Heat Under Pressure: How to Measure the Invisible
A superconductor is a material in which electricity flows without loss, like water through a perfectly smooth pipe. But if you squeeze it slightly, like a spring, its properties change. Scientists have long wanted to measure how much heat such a compressed material absorbs, but instruments couldn't fit into the cramped setup. Now they've devised a way around this obstacle.
Materials2026-08-142 minarXiv:2608.14502
The Crystal That Stopped Fearing Heat
A translator who has memorized all the lines in advance responds instantly — no need to listen to the whole conversation again. That's how the new model works: instead of running atoms through a computer for hours, it immediately outputs the crystal's free energy at any temperature and pressure.
HEP Theory2026-08-062 minarXiv:2608.05795express
The Third Law for a Black Hole
A black hole has three laws, just like an ideal gas. The first: energy is conserved. The second: the horizon area never decreases. And the third, the most finicky, demands that at zero temperature the entropy (a measure of disorder) tend to zero or a universal constant.
Strongly Correlated2026-08-042 minarXiv:2608.04098express
Strange Metal: When Pollen and Wind Get Tangled Together
The wind carries pollen, and each grain moves as if on its own. But once the air swirls into a vortex, the pollen trajectories can no longer be separated: they are tangled. This is roughly how electrons behave in a strange metal: their motion is so strongly coupled to soft fluctuations of the medium that the usual particle carriers disappear.
Materials2026-07-262 minarXiv:2607.23484express
Two Channels for Electric Current in Actinides
The river splits in two. One branch is wide and fast, with water flowing smoothly, but as temperature rises, the flow slows: eddies and waves appear. The second branch is narrow, with rapids, where water leaps from rock to rock. This flow, on the contrary, becomes more lively with warming.
Quantum Gases2026-06-091 minarXiv:2606.11338express
Three Faces of Quantum Cold
A pot of water always boils the same way: hit 100 degrees and bubbles start. Quantum fluids are different. When a cloud of atoms is cooled to near absolute zero, it can turn into a single matter wave — a Bose–Einstein condensate. But the transition itself, it turns out, can happen in three different ways.
High Energy2026-05-201 minarXiv:2605.20934express
How Atomic Jitter Keeps a Neutron Star's Superfluidity Alive
Imagine a packed dance floor where dancers glide without any friction — passing through each other without a touch. That's a superfluid. In a neutron star's crust, neutrons could behave this way, but a rigid lattice of ions gets in the way, like suddenly sticking the dance floor full of pillars.
HEP Theory2026-05-082 minarXiv:2605.08058express
Cosmic Doughnuts with a Gravity Filling
A mathematical doughnut, a torus, sits on the boundary of a three-dimensional world where gravity acts. You can crumple and stretch it, and physicists decided to see how it behaves. Inside this world, space can be flat like a table, expanding like a soap bubble, or curved like a saddle. The doughnut boundary refused to stay smooth.
Materials2026-04-261 minarXiv:2604.23491express
Plutonium That Heals Itself
Plutonium is a metal with attitude. One form shrinks when cooled, another swells. But at room temperature, the alloy behaves strangely: the ruler says one thing, X-rays say another. The ruler shows the sample barely grows, while X-rays see atoms in the crystal lattice moving further apart.
HEP Phenomenology2026-04-141 minarXiv:2604.12691express
How a quantum proton becomes a hot liquid
At the Large Hadron Collider, not only nuclei but also individual protons collide. Even in such small systems, collective behavior resembling the flow of a liquid is observed. But the proton is a quantum object; its state is described by a wave function, not by temperature and pressure.
Dynamical Systems2026-04-111 minarXiv:2604.10225express
Which Phases of Matter Are Real, and Which Are a Mirage
Water can be ice, liquid, or steam. Physicists call these states phases. In theory, each phase has its own measure — a way to describe how likely it is. But not every measure you can imagine occurs in nature. Some phases are real, while others are just mathematical illusions. Scientists have found a simple criterion that separates reality from mirage.
Statistical Mech2026-04-031 minarXiv:2604.02662express
Busting Myths About Bose–Einstein Condensate
In an orchestra where every musician plays the same note, the sound merges into a powerful unison. This is how a Bose–Einstein condensate is born: many boson particles at extremely low temperatures behave as a single entity.
Materials2026-03-271 minarXiv:2603.26855express
Bubbles vs. Pressure: Making Hydrogen Cheaper
Splitting water into hydrogen and oxygen with electricity is an age-old dream of clean fuel. But tiny gas bubbles stand in the way: they cling to the electrodes like foam on the side of a soda glass, interfering with the current's work. Each bubble is a tiny plug, blocking part of the surface where the reaction should occur.
Quantum Gases2026-03-071 minarXiv:2603.07121express
Order from Chaos: How Heat Gives Birth to a Crystal
Water in a pot, when heated, doesn't boil: it turns into ice. That's roughly how ultracold atoms behave in an optical lattice — a light-based crystalline grid that holds atoms in place. Scientists simulated this system on a computer to understand how order changes as temperature rises.
General Relativity2026-02-121 minarXiv:2602.11586express
Black Hole Did Not Destroy Quantum Entanglement
Fragile as ice in a furnace, quantum entanglement usually perishes from the slightest heat. Near a black hole, where space is twisted by Einstein's gravity and Hawking radiation Hawking's heats things up, any bond should be destroyed.
Materials2026-01-211 minarXiv:2601.14627express
A Thin Film Turns into a Ferroelectric
A cube of potassium tantalate behaves like an ordinary dielectric: it doesn't store an electric field. But grow this material as a thin film on a substrate of another crystal, and everything changes.
Quantum Physics2026-01-092 minarXiv:2601.05514express
A Wire Heats Up from Knowledge
Run a current through a wire, and the wire heats up. Anyone who has ever touched a phone charger knows this. Physicists call this heating Joule heating, after James Joule, who in the mid-19th century measured how much heat electricity produces. Since then, the formula has been simple: the greater the resistance and the current, the hotter the wire.