A class of crystalline materials with a specific structure, used in electronics and solar cells, often exhibiting hopping transport.Perovskite refers to a class of crystalline materials with the general formula ABX₃, where A and B are cations of different sizes and X is an anion (usually oxygen or a halogen). The name comes from the mineral calcium titanate (CaTiO₃), discovered in the Ural Mountains. Perovskites have a distinctive cubic crystal structure that can accommodate a wide variety of elements, leading to a remarkable range of physical properties, including ferroelectricity, superconductivity, and, most notably, excellent photovoltaic performance.
The perovskite structure was first described in 1839 by Gustav Rose, who named it after the Russian mineralogist Lev Perovski. The photovoltaic potential of hybrid lead halide perovskites was first demonstrated in 2009 by Tsutomu Miyasaka and colleagues, sparking a rapid surge in research.
The perovskite structure consists of a three-dimensional network of corner-sharing BX₆ octahedra, with the A cation occupying the large cavities between them. This flexible framework allows for easy substitution of different elements, which tunes the electronic band structure and optical properties. In solar cells, the material absorbs light efficiently due to its high absorption coefficient and long carrier diffusion lengths. Charge transport often occurs via hopping between localized states, especially in disordered or hybrid organic-inorganic perovskites, where the organic cation introduces dynamic disorder.
Perovskites are used in high-efficiency, low-cost solar cells, light-emitting diodes, photodetectors, and are being explored for use in lasers and radiation detectors.
Perovskite solar cells have achieved power conversion efficiencies exceeding 25% in just over a decade of research, a rate of improvement faster than any other photovoltaic technology.

















