A Diamond That Learned to Conduct Electricity ✎ express

Original: "The boron-hydrogen-phosphorus tri-elements co-doped stable N-type single crystalline Diamond"
arXiv:2604.22163 · 2026-04-24 · arXiv non-exclusive · independent analysis · 2 min
For the first time, a diamond with stable electronic conductivity has been grown, a step toward diamond electronics.

Diamond is the hardest natural material and usually does not conduct electricity. But if you add a few foreign atoms to its crystal lattice, it can become a semiconductor, like silicon in computer chips. The problem was that getting a diamond with stable electronic conductivity had failed: phosphorus, which 'donates' electrons, did not integrate well into the lattice, leaving too few free charge carriers.

A research group grew a diamond by adding three elements at once: boron, hydrogen, and phosphorus. The result was a crystal with several times more free electrons than phosphorus atoms. This means boron and hydrogen help phosphorus release electrons, as if one donor brought two assistants, and all three handed out electric charge. Measurements showed that the electron concentration reached $10^{19}$ per cubic centimeter, and the material's resistivity dropped to 0.249 Ω·cm — already the level of a good conductor.

Such a diamond also glows brightly in the ultraviolet range (270–285 nanometers), with an internal quantum efficiency of 69.4%. Ordinary diamond or diamond with only boron barely glows. This paves the way for diamond-based LEDs and lasers operating in the ultraviolet, as well as powerful, fast electronics that do not overheat.

The donor level in such a diamond lies at a depth of only 61.6 meV, as if an electron sat on the top step of a staircase, needing just a little energy to jump off and run through the crystal.

The researchers did not just add impurities: they found a way to make them work together. Previously, it was thought that phosphorus alone would suffice, but it was 'lazy.' Now, the three elements act in concert, turning diamond from an insulator into a semiconductor with good conductivity. It is like assembling a team where each member amplifies the others.

Diamond conducts heat better than any material — five times better than copper. Therefore, diamond chips could operate at frequencies unattainable for silicon without melting.

Such a material could become the basis for transistors operating at high temperatures and voltages, for ultraviolet detectors, and even for quantum devices. And all of this comes from a single crystal grown in one step.

Diamond conducts heat five times better than copper, so diamond chips could run at frequencies unattainable for silicon without overheating.

Scientists
Klaus von KlitzingLev LandauJohn BardeenShuji NakamuraFred HoyleMargaret Burbidge
Concepts
doping hole doping diamond europium phosphorus diamond anvil cell molybdenum boron boron nitride heralded single photon generation invention of the blue LED silicon diamond nv center argon