The blue LED is a light-emitting diode invented using europium for brighter and more stable blue light.The path to the blue LED took several decades. The main difficulty: obtaining a semiconductor with a bandgap of about 3.4 eV (corresponding to blue light) and doping it p-type (adding impurities to create hole conductivity). Shuji Nakamura at the Japanese company Nichia first created high-quality GaN films on a sapphire substrate and developed a thermal annealing method to activate magnesium acceptors, obtaining p-GaN. In 1993, he demonstrated a bright blue LED, and later — the first blue laser.
In the 1970s, Jacques Pankove (RCA) obtained the first blue emission from GaN, but without p-doping. In 1986, Isamu Akasaki and Hiroshi Amano first created p-GaN using electron-beam irradiation. Shuji Nakamura, working independently at Nichia, in 1993 applied thermal annealing and developed a structure with a double heterostructure InGaN/GaN, which led to a commercially successful blue LED. In 2014, Akasaki, Amano, and Nakamura received the Nobel Prize 'for the invention of efficient blue light-emitting diodes which has enabled bright and energy-saving white light sources'.
Blue LEDs serve as the foundation for solid-state lighting (LED lamps) and displays (OLED, microLED). They are also used in laser diodes for Blu-ray drives (λ=405 nm) and Li-Fi systems (visible light communication). Limitations: efficiency still drops at high current densities ('droop'), and there are degradation issues during prolonged operation.
Thanks to the blue LED, we have energy-efficient LED lighting, phone and TV screens with full color gamut, and laser projectors.
Shuji Nakamura was awarded the Nobel Prize in 2014, but his company Nichia initially paid him a bonus of just $200 for the invention, after which a long legal battle ensued.



