Quantum Pairs: How Defects in a Crystal Change the Game express

Original: "Interacting donor-acceptor pairs as the origin of coupled spin-optical signals in hexagonal boron nitride"
arXiv:2605.20655 · 2026-05-20 · CC BY 4.0 · 2 min
Neighboring atomic defects in a crystal work as a pair, not individually, and this explains the mysteries of their luminescence.

In a boron nitride crystal, the perfect atomic lattice is sometimes disrupted: an atom is missing here, or replaced by a foreign one there. Under a powerful microscope, these tiny imperfections appear as traps for electrons: they capture particles and start to emit light, and they also respond to magnetic fields. It is precisely such defects that promise to become the foundation for quantum technologies operating at ordinary room temperature, without bulky refrigerators.

For a long time, it was believed that each defect was a loner. But supercomputer calculations revealed a different picture: defects often live in pairs, like two communicating vessels. One of them is a donor with an extra electron, the other is an acceptor that lacks an electron. The electron jumps from the donor to the acceptor, and the distance between them determines everything: the color of the emitted light, its brightness, and how long it lasts. By changing this distance, one can tune the quantum properties of the pair, as if turning a tuning knob.

A pair of defects resembles two dancers who spin closer and then farther apart: when they come together, their joint dance accelerates, and when they move apart, each begins to move in its own rhythm.

When there are many such pairs in the crystal, they begin to influence each other, creating entire ensembles. This explains why different laboratories obtained such contradictory results: researchers were seeing the emission not of individual defects but of entire collectives, where each pair contributed its share. Now, with this knowledge, one can not guess but precisely design the desired configurations of defects — for example, to obtain a perfectly stable source of single photons for quantum communication.

Interestingly, the sign of the optically detected magnetic resonance, a key signal for quantum applications, can flip depending on how the charge is redistributed within the pair.

Boron nitride is sometimes called 'white graphene' due to its similar layered structure, but unlike graphene, it does not conduct electricity, making it an ideal platform for isolating quantum defects.

Scientists
Erwin SchrödingerHugh Everett IIIChristian DopplerD. B. McLaughlinDidier QuelozMichel Mayor
Concepts
electron pairs boron nitride hexagonal boron nitride photon pair radical pair spin orbit coupling semiconductor light interaction photonic integrated circuit entangled photon pairs optical chip triplet superconductivity exchange coupling exciton nuclear spin synchrotron radiation optical switch exchange interaction superconducting gap doping Cooper pair