A crystalline form of boron nitride with a hexagonal lattice structure, used here as a host for quantum sensor defects.Hexagonal boron nitride (h-BN) is a crystalline compound of boron and nitrogen arranged in a two-dimensional honeycomb lattice, structurally analogous to graphene. Unlike graphene, which is a conductor, h-BN is an excellent electrical insulator with high thermal conductivity and chemical stability. In quantum sensing, h-BN is valuable as a host material for atomic-scale defects — imperfections in the lattice that can act as quantum sensors, emitting and absorbing light in ways sensitive to magnetic fields, temperature, and strain.
Hexagonal boron nitride was first synthesized in the 19th century, but its use as a quantum sensor host emerged in the 2010s, following the discovery of optically active defects in its monolayer form. The specific identification of boron vacancy defects as quantum sensors was reported around 2019.
The key to h-BN's role is its wide bandgap, which allows certain defects (such as boron vacancies) to have optically addressable spin states. When a defect absorbs a photon, it transitions to an excited state; the spin of the defect's electron can be manipulated with microwave pulses, and the emitted light intensity depends on the spin state. This spin-photon interface enables readout of the local environment, as external fields alter the spin energy levels and thus the fluorescence. The hexagonal lattice provides a stable, low-noise matrix that preserves the quantum coherence of the defects, even at room temperature.
h-BN quantum sensors are used in nanoscale magnetometry, thermometry, and electric field imaging, particularly in biological samples or 2D material heterostructures where their atomic thinness and chemical inertness are advantageous.
Hexagonal boron nitride is often called 'white graphene' because it shares graphene's honeycomb structure but is electrically insulating and appears white in bulk form.










