A technique that uses light to detect magnetic resonance signals from defects, used for quantum sensing.Optically detected magnetic resonance (ODMR) is a technique that combines magnetic resonance with optical readout to detect and manipulate quantum states in certain solid-state defects, most notably the nitrogen-vacancy (NV) center in diamond. It works by using laser light to initialize and read out the spin state of the defect, while microwave radiation drives transitions between spin levels. The technique is central to quantum sensing, enabling measurements of magnetic fields, electric fields, temperature, and pressure with nanoscale spatial resolution and high sensitivity.
The technique was first demonstrated in the 1960s for color centers in solids, but its application to NV centers in diamond was pioneered in the late 1990s by groups such as Jörg Wrachtrup and Fedor Jelezko, who showed coherent control and optical readout of single NV spins.
The process begins with a laser pulse that excites the defect into a state whose fluorescence intensity depends on the spin state. In the NV center, the ground state has two spin sublevels (ms=0 and ms=±1). The ms=0 state fluoresces more brightly than the ms=±1 states. By sweeping microwave frequencies and monitoring fluorescence, one observes a dip in fluorescence when the microwave frequency matches the energy splitting between spin levels (the resonance condition). This resonance frequency shifts in the presence of external fields, allowing precise measurement of those fields. The optical readout provides a sensitive, non-destructive way to detect the spin state, bypassing the need for electrical contacts.
ODMR is used in quantum sensors for magnetometry (e.g., mapping magnetic fields in materials or biological cells), thermometry at the nanoscale, and in emerging quantum information technologies like spin-based qubits for quantum computing.
ODMR-based diamond sensors can detect the magnetic field of a single electron spin, and they have been used to image the magnetic fields produced by neurons firing in living organisms.
























