Age is the most important and most elusive parameter of a star. Without it, we cannot reconstruct the history of the Galaxy. Cecilia Payne-Gaposchkin showed that stars are mostly hydrogen and helium, and Fred Hoyle and Margaret Burbidge explained how nuclear reactions inside them forge elements. The abundance ratios of certain elements, such as yttrium and magnesium, change predictably due to their different sources and injection timescales into the interstellar medium. This led to the idea of 'chemical clocks.' However, previous studies have shown that these clocks tick differently in various parts of the Galaxy. This work expands the sample and, for the first time, extensively uses precise asteroseismic ages for calibration, while correcting systematics arising from departures from thermodynamic equilibrium (non-LTE).
For 528 field stars from the TESS mission, spectra were obtained using high-resolution spectroscopy with the VUES spectrograph (resolution ~68,000) at the Molėtai Observatory. Spectral synthesis was used to measure Mg and Y abundances with non-LTE corrections. Ages were determined in two ways: for 307 stars—asteroseismically (by analyzing solar-like oscillations: measuring the frequency of maximum power and the large separation), and for the rest—via the isochrone method (comparison with evolutionary tracks). Asteroseismic ages were verified with the SPInS code and showed good agreement. Classification into thin and thick disk was done rigorously: based on kinematics (U, V, W velocities using the Doppler effect), membership probabilities, and alpha-element enrichment (Mg). All parameters are compiled in a final catalog.
The [Y/Mg]-age relation shows clear spatial variations. In the outer disk region (R > 8.5 kpc), the slope is steepest: log Age = –7.092 [Y/Mg] + 9.206 with a Pearson correlation coefficient of –0.60. Toward the Sun (7.5–8.5 kpc), the slope decreases, and in the inner disk (R < 7.5 kpc) the trend is nearly flat (PCC = –0.22). The thick disk shows almost no correlation (PCC = –0.20), indicating rapid formation before significant AGB star contribution. Splitting by metallicity reveals that stars with [Fe/H] > –0.2 have, on average, higher [Y/Mg] across all ages, but for stars with [Fe/H] > 0.1, the trend flattens: at young ages, [Y/Mg] is lower than for solar-metallicity stars. This agrees with theoretical expectations: at high metallicity, there are fewer neutrons per iron seed, and the s-process produces more light elements, including yttrium, which saturates the clock.
The results mean that Galactic chemical clocks are not universal: their calibration must account for a star's birthplace. The transition from a flat relation in the thick disk to a steep one in the outer thin disk reflects a radial gradient in star-formation efficiency. The inner regions formed quickly and became saturated with elements, while the outer regions evolved more slowly, allowing the s-process to accumulate yttrium. This is direct observational evidence that Galactic evolution proceeded differently at different radii. For chemical evolution theory, this requires a revision of models that assume homogeneous enrichment.
In the future, machine learning methods will enable multidimensional calibrations that simultaneously account for age, metallicity, position, and kinematics. Similar studies are planned for other pairs (Ba/Mg, Ce/Mg), although for barium, the 'barium puzzle'—the difficulty of analyzing its lines—poses a challenge. An important step will be integration with Gaia data and future missions like PLATO, which will provide asteroseismic ages for thousands of stars.
The results will impact stellar astrophysics, Galactic archaeology, age determination methods, and chemical evolution models.
The next step is to apply the method to open clusters with precisely known ages and to red clump stars to refine the spatial trends. It is also necessary to include more stars from the inner disk to confirm the flattening at super-solar metallicities.
The research connects to open questions: the origin of s- and r-process elements, the formation of galactic disk structure, and the age of the Universe problem (local clocks must agree with cosmological ones). It also touches on the issue of convective mixing in AGB stars and nucleosynthesis beyond iron.
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What the work does
The study measured yttrium and magnesium abundances with non-LTE corrections for 528 TESS field stars, with ages for some determined asteroseismically and the rest via isochrone fitting. The [Y/Mg]–age relation is shown to vary with Galactocentric distance and metallicity, while being essentially absent in the thick disk.
Where its strength is
The large-scale application of asteroseismic ages for calibrating chemical clocks, combined with careful accounting for non-LTE effects, provides a robust foundation for studying the spatial inhomogeneity of disk evolution.
Where it could go next
Worth trying
Why this may matter
Spatially calibrating chemical clocks turns the [Y/Mg] ratio into a tool for reconstructing the star formation history in different parts of the disk, which is key to understanding the assembly of the Milky Way.
Nearby works in our archive
The closest work in the archive sits at 0.68 by meaning — the usual level for our corpus.
as written by the authors arXiv:2607.15017
Building on our previous study, which demonstrated the importance of accounting for departures from local thermodynamic equilibrium (LTE) in elemental-abundance determinations and of using asteroseismic ages, we investigate spatial variations in the empirical [Y/Mg]-age relation across the Galactic disc using a substantially larger stellar sample. We analysed high-resolution stellar spectra and determined Mg and Y abundances through spectral synthesis of multiple spectral features, rigorously accounting for non-LTE (NLTE) effects. We derived asteroseismic ages for stars exhibiting solar-type oscillations and used cross-checked isochrone-based methods for the remaining stars. We determined atmospheric parameters and Mg and Y abundances for 528 Galactic field stars, together with asteroseismic ages for 307 stars and isochronal ages for 221 stars. We also identified two new triple-lined and nine double-lined spectroscopic systems. Combining the present sample with that of our previous study yielded a total of 736 stars, which we used to examine the [Y/Mg]-age relation across the Galactic disc. The relation shows systematic spatial variations that likely reflect differences in star-formation and chemical-enrichment histories. In general, [Y/Mg] tends to increase with metallicity over the investigated age range. At supersolar metallicity, however, this trend may weaken, and the [Y/Mg]-age relations become flatter than those of solar-metallicity stars, which show lower [Y/Mg] values at young ages and higher values at old ages.
Yttrium, used as a chemical clock, is named after the Swedish village of Ytterby, where a mineral containing this element was found. Magnesium, one of the most common metals in Earth's crust, is born mostly in Type II supernovae. So the clock ticks thanks to explosions and slow burning in stars.