The periodic motion of atoms within a molecule, which absorbs specific frequencies of light.Molecular vibration is the periodic motion of atoms within a molecule, where bonds stretch, bend, and twist around their equilibrium positions. These vibrations occur at specific frequencies, typically in the infrared region of the electromagnetic spectrum. When infrared light matches a vibrational frequency, the molecule absorbs that light, providing a unique spectral fingerprint. This phenomenon is the basis of infrared spectroscopy, a powerful tool for identifying molecules and studying their structure and environment.
The concept of molecular vibrations was developed in the late 19th and early 20th centuries with the advent of quantum mechanics. Infrared spectroscopy was first used systematically in the 1930s, and the theory of normal modes was formalized by physicists like Max Born and Theodore von Kármán.
A molecule with N atoms has 3N-6 vibrational modes (or 3N-5 for linear molecules). Each mode corresponds to a collective motion of atoms, such as symmetric stretching or bending. The frequency of each mode depends on the masses of the atoms and the strength of the bonds. When infrared light hits the molecule, it is absorbed if its frequency matches a vibrational mode, causing the molecule to jump to a higher vibrational energy state. The absorption spectrum reveals which modes are active and at what frequencies, allowing chemists to infer molecular structure and bonding.
Infrared spectroscopy is used in chemistry, biology, and materials science to identify unknown substances, monitor chemical reactions, and study molecular interactions—for example, in the article 'Как вода танцует с углеродными кольцами: спектроскопия молекулярного д'.
The vibrational frequency of a bond can be used to measure its strength: stronger bonds vibrate faster, which is why the stretching vibration of a triple bond appears at a higher frequency than that of a double bond.



