The push to miniaturize active particles down to atomic scales confronts the dominance of quantum effects. Just as Einstein explained Brownian motion, modern active matter research aims to understand particles that draw energy from their surroundings. At the atomic level, however, classical mechanisms give way to quantum ones: Schrödinger evolution of the wavefunction and wave–particle duality become decisive. This work for the first time realizes activity at the scale of individual atoms, using quantum spin exchange to create directed motion.
The experiment was carried out with an ensemble of about 68 cesium-133 atoms, trapped in an optical dipole trap and immersed in an ultracold cloud of 7700 rubidium-87 atoms at a temperature of about 460 nanokelvin, close to the conditions for Bose–Einstein condensation. Activation was provided by inelastic s-wave spin-exchange collisions, with cross sections calculated from first principles using the Schrödinger equation within a multichannel approach. In each such collision, the Zeeman energy difference of two hyperfine states (Zeeman effect) is released as kinetic energy, while the reverse (endothermic) processes are suppressed due to the ultralow collision energies, leading to a violation of the second law of thermodynamics at the microlevel—effectively a breakdown of detailed balance. The quantum nature of scattering further enhances activation: high-energy atoms have a lower collision probability, prolonging their free path. For modeling, two complementary approaches were used: numerical simulation with an event-based Monte Carlo method and a coarse-grained active Langevin model derived from kinetic theory.
The spin-exchange collisions cause a significant transient broadening of the spatial distribution of cesium atoms: its width can exceed the passive case by a factor of 4 at a magnetic field of 3 G, corresponding to an activation energy Q ≈ 51 μK—two orders of magnitude larger than the bath's thermal energy. The broadening is temporary, since the spin-state spectrum of cesium is limited (maximum 6 exothermic collisions), after which the atom thermalizes via elastic collisions. The dynamics agree excellently, without free parameters, with predictions from both quantum-mechanical cross-section calculations in Monte Carlo simulations and the active Langevin model, confirming that cesium atoms behave as classical active Brownian particles but with a quantum energy source. Increasing the temperature of the rubidium bath weakens the effect because the relative contribution of the activation energy decreases.
This work turns ultracold atomic mixtures into a controllable platform for quantum thermodynamics of active matter. It enables experimental exploration of fundamental questions, such as entropy production in nonequilibrium quantum systems and the limits of applicability of fluctuation–dissipation theorems. Moreover, the system can serve as a testbed for studying quantum decoherence in active media, since the interaction with the environment (the rubidium bath) is well described by the Markov approximation.
Further cooling of the system will enhance quantum superpositions and matter-wave effects, allowing observation of competition between activity and localization in changing potentials. Restoring the spin state of cesium via radio-frequency radiation could extend the active period, and increasing the number of active atoms will open the door to collective quantum phenomena such as flocking or mobility-induced phase separation. In the future, such systems may find applications in quantum information technologies, for example in reservoir computing.
Beyond the physics of active media and statistical mechanics, the technique will impact ultracold quantum chemistry and quantum-state engineering. The ability to precisely control energy exchange between internal and external degrees of freedom of individual particles is valuable for quantum simulators and sensors.
Near-term steps include experiments with a larger number of cesium atoms to observe collective effects, as well as a transition to a degenerate rubidium gas, where anomalous diffusion and long-lived correlations may radically alter the active dynamics.
The realized system touches on key unsolved problems in physics: the microscopic origin of the arrow of time through entropy production in the quantum limit, the role of the observer in the quantum dynamics of open systems, and the problem of quantum thermalization. Boltzmann sought to explain irreversibility through statistics, and today quantum active matter offers a new angle on this fundamental puzzle.
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What the work does
The work demonstrates active matter at the level of individual atoms: cesium atoms embedded in an ultracold rubidium cloud acquire directed motion through quantum spin-exchange collisions that break detailed balance at ultralow energies. The experimental results agree with Monte Carlo models and the active Langevin equation without any fitting parameters.
Where its strength is
The key strength is the first demonstration of activity at the atomic scale with precise quantum-mechanical control of the energy source and a predictive model with no free parameters, opening the way to studying nonequilibrium thermodynamics in the quantum limit.
Where it could go next
Worth trying
Why this may matter
Such a system could serve as a quantum simulator of nonequilibrium processes, allowing us to probe fundamental questions of thermodynamics at the microscopic level and potentially create new types of quantum devices.
Nearby works in our archive
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as written by the authors arXiv:2606.24615
Active matter comprises particles that extract energy from their local environment and convert it into motion. Although active particles have been miniaturized down to the nanoscale, realizing activity at the fundamentally smaller scale of individual atoms remains an open challenge, where quantum effects become increasingly relevant. Here, we experimentally demonstrate that individual Cs-133 atoms confined in an optical dipole trap extract energy from an ultracold bath of Rb-87 atoms via quantum-mechanical spin interactions and convert it into active motion. We quantitatively reproduce the resulting dynamics using a parameter-free active Langevin model derived from kinetic theory and support it with event-driven Monte Carlo collision simulations. The microscopic origin of activity is identified as quantum spin exchange, which transfers discrete internal spin energy into kinetic motion. Our work establishes a quantum-enabled route to active matter at the fundamental size limit of single atoms and opens perspectives for exploring the interplay of activity, quantum physics, and mesoscopic non-equilibrium thermodynamics.
Colder than space: the temperature of the rubidium cloud (460 nK) is millions of times lower than that of the cosmic microwave background, yet the cesium atoms inside it are accelerated to velocities comparable to thermal speeds at room temperature.