
A change in an atom's energy state, often involving the absorption or emission of a photon.An atomic transition is a change in the energy state of an atom, typically involving the absorption or emission of a photon. When an electron moves from a higher energy level to a lower one, the atom releases a photon with a specific frequency; conversely, absorbing a photon can boost the electron to a higher level. These transitions are the fundamental mechanism behind many phenomena, from the colors of glowing gases to the precise ticking of atomic clocks.
The concept of quantized energy levels and transitions was formalized by Niels Bohr in 1913, building on Max Planck's quantum hypothesis. The modern quantum mechanical description was developed in the 1920s by Erwin Schrödinger and Werner Heisenberg.
The energy levels of an atom are quantized, meaning electrons can only occupy specific discrete orbits. A transition occurs when an electron jumps between these allowed levels, and the energy difference between the levels determines the frequency of the photon involved. This frequency is highly stable and unique to each element, making atomic transitions a reliable 'ruler' for measuring time and frequency.
Atomic transitions are used in atomic clocks, which define the international standard for time (the cesium-133 transition), and in lasers, where stimulated emission from transitions produces coherent light. They also underpin spectroscopy, used to identify elements in stars and materials.
The 'second' is officially defined as exactly 9,192,631,770 oscillations of the microwave transition between two energy levels of a cesium-133 atom.









