Wave-particle duality is the quantum property where entities like photons or electrons exhibit both wave-like and particle-like behavior.Light is a universal actor: in the role of a wave, it bends around obstacles and paints rainbow rings; in the role of a particle, it knocks electrons out of metal, giving rise to an electric current. Any particle, even an electron or a massive molecule, possesses both roles.
Louis de Broglie put forward a revolutionary hypothesis in 1924 about the wave properties of matter, assigning a wavelength λ = h/p to any moving particle. Erwin Schrödinger in 1926 built on this by creating wave mechanics, describing particles as waves distributed in space. The experiments of Davisson and Germer (1927) and independently G.P. Thomson with electrons confirmed the prediction, demonstrating electron diffraction by crystals.
The duality is quantitatively expressed through Heisenberg's uncertainty principle: Δx·Δp ≥ ħ/2. The more precisely the particle characteristic (momentum) is measured, the more blurred the wave characteristic (position) becomes. The wave function ψ(x) contains complete information about the system, and its squared modulus gives the probability of finding the particle at a point. The Schrödinger equation governs the evolution of the wave pattern, and measurement collapses it into a localized particle.
Scientists passed huge fullerene molecules (almost a millimeter in size) through two slits and obtained interference patterns—the molecules behaved like waves, even though you could touch them.
| ψ | variable | Quantum wave function — wave function metre to the minus 3 over 2 |
| R | variable | Real amplitude of the wave function — probability amplitude metre to the minus 3 over 2 |
| S | variable | Phase of the wave function (action) — action joule second |
| ℏ | constant | Fundamental constant setting the scale of quantum phenomena — reduced planck constant = 1.054571817e-34 joule second |
| e^{iS/ℏ} | operator | Complex phase factor encoding the oscillatory behaviour — complex exponential |
| \psi | variable | wave function — wave function |
| x | variable | position coordinate — position metre |
| k | variable | wave number — wave number per metre |
| V(x) | variable | potential function — potential energy joule |
| \frac{d^2}{dx^2} | operator | second derivative with respect to position — second derivative |














