law

first law of thermodynamics

The first law of thermodynamics states that energy cannot be created or destroyed, only transformed or transferred.
6 related articles · 1 formulas

Description

Energy does not appear from nowhere and does not disappear without a trace — it only changes from one form to another. The first law of thermodynamics is like a bank account: the change in your savings equals the sum of deposits minus withdrawals. The same principle in physics: the change in internal energy of a system equals the heat added minus the work done.

History

The law was formed by the efforts of several scientists in the mid-19th century. Julius Robert von Mayer in 1842 first formulated the principle of conservation of energy based on observations of blood color in the tropics. James Prescott Joule in 1843-1845 experimentally measured the mechanical equivalent of heat, proving that heat is a form of energy. Hermann von Helmholtz in 1847 generalized the law to all forms of energy. Rudolf Clausius in 1850 introduced the concept of internal energy and gave the first rigorous mathematical formulation for heat engines.

How it works

The law is the basis of all technical thermodynamics: calculation of engine cycles, refrigerators, chemical reactions. It is applicable to macroscopic systems in a state of thermodynamic equilibrium or close to it. Limits: for relativistic processes, the mass-energy equivalence (E=mc²) must be taken into account; for microscopic systems, quantum fluctuations are important.

Fun fact

The human body is a heat engine: all the energy from food eaten is spent on muscle work, heat release, and stored in fat. You never get more energy than you consumed.

Concept graph →

Formulas

$$dU = \delta Q - \delta W$$
Change in internal energy equals heat added minus work done.
What is in the formula
dUvariableInfinitesimal change in internal energy — internal energy joule
δQvariableInfinitesimal heat added to the system — heat joule
δWvariableInfinitesimal work done by the system — work joule
doperatorExact differential of a state function — exact differential
δoperatorInexact differential for path-dependent quantities — inexact differential
de=tds-pdv · 2607.03749

Related articles · 13

Materials2026-08-142 minarXiv:2608.14502
The Crystal That Stopped Fearing Heat
A translator who has memorized all the lines in advance responds instantly — no need to listen to the whole conversation again. That's how the new model works: instead of running atoms through a computer for hours, it immediately outputs the crystal's free energy at any temperature and pressure.
General Relativity2026-08-021 minarXiv:2608.01152express
The Hidden Twin of a Black Hole's Spin
The Kerr-NUT black hole is not just a cosmic vacuum cleaner. It's a solution to Einstein's equations where the hole has mass, rotation, and a strange NUT parameter. This parameter behaves like a magnetic charge for gravity: seemingly invisible, yet it alters the properties of surrounding space.
The Shadow Breath of a Neutron Star: Axions and the X-ray Puzzle
Some 123 parsecs from Earth, in the constellation Corona Australis, drifts the neutron star RX J1856.5-3754. Its diameter is about 12 kilometers, smaller than Moscow's Ring Road, but its surface temperature reaches 460 000 kelvin. The star emits a slow, almost inaudible exhalation.
HEP Phenomenology2026-07-212 minarXiv:2607.19469express
Why Bubbles Don't Immediately Turn into Matter
Boiling water in a pot is a good place to start. Bubbles of steam rise, pop, and the surface settles down. Something similar might have happened in the first moments of the universe's life with a special field filling space: bubbles of a new phase inflated and collided, like islands of steam in liquid.
Entropy Symphony: How ACT Tuned Inflation
A new tuning fork for the cosmic symphony sounded from the Chilean highlands: the ACT telescope refined the note of primordial perturbations — the spectral index nₛ shifted upward, disrupting the harmony of many previous models.
Materials2026-06-273 minarXiv:2606.29055
Diamond Storm: Birth of Quantum Vortices from the Void
Diamond is a symbol of perfection, but its true magic is revealed through flaws. Perfect lattice purity gives transparency and hardness, while defects, such as color centers, open a portal to the quantum world, becoming the foundation for quantum computers and quantum sensors.
Quantum Physics2026-05-162 minarXiv:2605.17196express
Maxwell's Demon and the Quantum Guardian of Heat
In 1867, James Clerk Maxwell proposed an image that still stirs physicists today. Two compartments of gas are separated by a door. Molecules dart about chaotically: fast and slow. A tiny gatekeeper opens the door only for fast ones, letting them through to one side, and slow ones to the other. The hot compartment gets hotter, the cold one colder.
Quantum Physics2026-05-142 minarXiv:2605.15339express
Quantum Energy Dance: Equilibrium Without Rest
A pot of soup forgotten on the stove cools to room temperature. It seems everything has come to rest. But if you look inside with a quantum magnifying glass, you'll find that water molecules haven't frozen: they continue their dance. It's just that now the dance is steady, not turbulent like when boiling.
Quantum Physics2026-04-092 minarXiv:2604.08663express
How to Catch Quantum Magic with Plain Heat
A quantum system can possess a property called magic. It's not about tricks: it's a measure of how hard it is to reproduce its behavior on a classical computer. Ordinary states, known as stabilizer states, are easy for a computer to handle. But states with magic leave it stumped.
Statistical Mech2026-03-071 minarXiv:2603.07128express
Water Works on a One-Degree Difference
An ordinary heat engine is like a mill between the hot and cold banks of a river: the greater the drop, the stronger the current. Here, the drop is tiny, just one or two degrees, but water can still turn the wheel. The secret is that water is made to boil not by heating but by a sudden drop in pressure, so steam bursts out even from barely warm liquid.
Quantum Physics2026-01-011 minarXiv:2601.00198express