equation

Schrödinger equation

The Schrödinger equation describes how the quantum state of a physical system changes with time.
58 related articles · 6 formulas · 2 who worked here

Description

In the quantum world, particles behave like waves of probability. The Schrödinger equation is a mathematical rule that tells how these waves change over time. It does not indicate the exact location of a particle but gives probabilities: for example, where an electron is most likely to appear. It's like a weather forecast that predicts where rain is most likely.

History

Erwin Schrödinger published the equation in 1926, building on the work of Louis de Broglie (1924) on matter waves. The first success was explaining the spectrum of the hydrogen atom. Soon after, Max Born gave a statistical interpretation of the wave function, and John von Neumann developed a rigorous mathematical formalism in Hilbert space. The Schrödinger equation is still widely used, although for relativistic particles the Dirac equation is used.

How it works

Applied for calculating energy levels of atoms and molecules, band structure of crystals, dynamics of quantum systems. Limits: not applicable at speeds close to the speed of light (replaced by the Dirac equation), does not describe particle creation and annihilation (for this, second quantization and quantum field theory are used).

Fun fact

Without the Schrödinger equation, there would be no modern semiconductors, lasers, or even quantum computers — all of these work on quantum principles.

Concept graph →

Formulas

$$i\hbar\frac{\partial\psi}{\partial t} = -\frac{\hbar^2}{2m}\nabla^2\psi + V\psi$$
Describes quantum particles with self-gravitating potential.
What is in the formula
ψvariablewave function of the quantum particle — wave function metre to the minus 3 over 2
tvariabletime — time second
Vvariablepotential energy (here self-gravitating) — potential energy joule
mvariablemass of the particle — mass kilogram
ħconstantReduced Planck constant, fundamental quantum of action — reduced planck constant = 1.054571817e-34 joule second
∂/∂toperatorpartial derivative with respect to time — partial derivative
∇²operatorLaplacian (spatial second derivative) — laplacian operator
iħ\partial_tψ=[-\frac{ħ^2}{2m}\nabla^2-gm^2\int\frac{|ψ(y)|^2}{|x-y|}d^3y]ψ · 2605.06577v1
$$\frac{d^2\psi}{dx^2} + \left(k^2 - V(x)\right) \psi = 0$$
Wave equation with potential barrier in quantum mechanics.
What is in the formula
\psivariablewave function — wave function
xvariableposition coordinate — position metre
kvariablewave number — wave number per metre
V(x)variablepotential function — potential energy joule
\frac{d^2}{dx^2}operatorsecond derivative with respect to position — second derivative
\frac{d^2u}{dr_*^2}+(ω^2-v_{{eff}}(r))u=0 · 2605.09426v1
$$-\frac{d^2 \psi}{dx^2} + V(x) \psi = E \psi$$
A wave function's evolution in a potential is governed by the Schrödinger equation.
What is in the formula
ψvariablewave function — wave function
xvariableposition coordinate — position metre
V(x)variablepotential energy function — potential energy joule
Evariableenergy eigenvalue — energy joule
d²/dx²operatorsecond derivative with respect to position — second derivative
-\frac{d^2h}{d\eta_*^2}+v(\eta_*)h=ε^2ω^2h · 2605.11565v1
\hat{h}ψ=eψ · 2606.22926
iħ\frac{\partialψ}{\partialt}=(-\frac{ħ^2}{2m}\frac{\partial^2}{\partialx^2}+v(x)-iw(x))ψ · 2607.03845
iħ\frac{\partialψ}{\partialt}=-\frac{ħ^2}{2m}\nabla^2ψ+m\phiψ · 2607.16917v1
$$\oint p \, dq = n h$$
Quantization condition for action integrals in old quantum theory.
What is in the formula
pvariablecanonical momentum — momentum kilogram metre per second
qvariablecanonical coordinate — position metre
nvariablequantum number (integer) — quantum number
hconstantfundamental constant relating energy to frequency — planck constant = 6.62607015e-34 joule second
∮operatorintegral over one full period of the motion — closed line integral
\ointpdx=nh · 2606.28640
$$\frac{d\rho}{dt} = -\frac{i}{\hbar}[H,\rho] + \sum_n \left( L_n \rho L_n^\dagger - \frac{1}{2} \{ L_n^\dagger L_n, \rho \} \right)$$
Describes open quantum system evolution with dissipation.
What is in the formula
ρvariabledensity matrix of the open quantum system — density matrix
tvariabletime — time second
HvariableHamiltonian of the system — hamiltonian joule
L_nvariableLindblad operators (jump operators) for each dissipation channel — lindblad operator
iconstantimaginary unit, square root of -1 — imaginary unit = 1
ħconstantPlanck constant divided by 2π — reduced planck constant = 1.054571817e-34 joule second
d/dtoperatorderivative with respect to time — time derivative
[H, ρ]operatorcommutator of H and ρ — commutator
{L_n† L_n, ρ}operatoranticommutator of L_n† L_n and ρ — anticommutator
∑_noperatorsum over all dissipation channels — sum over channels
\frac{dρ}{dt}=-\frac{i}{ħ}[h_0,ρ]+2γ(\barn+1)\mathcal{d}[b]ρ+2γ\barn\mathcal{d}[b^\dagger]ρ+2k\mathcal{d}[f(x)]ρ · 2505.01942v2
l_{{rot}}\hat{σ}=-\frac{1}{2ħ^2}\intd^3xd^3yd^{kl}_a(\vec{x},\vec{y})χ_{ki;lm}(\vec{x},\vec{y})[\hat{l}_i,[\hat{l}_m,\hat{σ}]] · 2605.12172v1
\frac{dρ}{dt}=-\frac{i}{ħ}[h,ρ]+\sum_k(l_kρl_k^\dagger-\frac{1}{2}\{l_k^\daggerl_k,ρ\}) · 2607.09247
$$\Delta X \propto \cos[2(\theta - \theta_0)]$$
A physical quantity varies as the cosine squared of an angle offset.
What is in the formula
\Delta XvariableChange in a physical quantity — physical quantity change
\thetavariableAngle variable — angle radian
\theta_0variableReference angle offset — angle radian
\proptooperatorIndicates the left side scales with the right side — proportionality
\cosoperatorComputes the cosine of an angle — cosine function
δr\propto\cos[2(α-α_0)] · 2510.15091

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