Carnot's theorem states that no heat engine operating between two reservoirs can be more efficient than a Carnot engine.In 1824, French engineer Sadi Carnot, pondering the improvement of steam engines, arrived at a fundamental theorem. He realized that the maximum efficiency of any heat engine is determined solely by the temperatures of the heater and the cooler and does not depend on the working substance. The idea came from an analogy with a water mill: the work is determined not by the mechanism but by the difference in levels. Carnot introduced the concept of a reversible cycle where there are no losses due to friction, etc., and proved that all reversible engines have the same efficiency, and irreversible ones have less. This result later formed the basis of the second law of thermodynamics.
Sadi Carnot in 1824 published a treatise 'Reflections on the Motive Power of Fire', where he described an idealized heat cycle and derived his theorem. His work remained little known until William Thomson (Lord Kelvin) in 1848 realized its significance for formulating the second law of thermodynamics. Rudolf Clausius mathematically justified Carnot's result by introducing the concept of entropy in the 1850s. Thus, Carnot's theorem became the starting point for the development of thermodynamics as a science.
The theorem is used as a benchmark for evaluating the efficiency of real heat engines: steam turbines, internal combustion engines, refrigeration units. Its range of applicability: valid for systems where reservoir temperatures are kept constant, processes are quasistatic, and dissipative losses are absent. It breaks down when considering finite process speeds, as well as in microscopic systems where fluctuations become significant.
Car engines and power plants operate more efficiently the greater the temperature difference between fuel combustion and exhaust; increasing this difference is a direct engineering task.
The efficiency of even an ideal gasoline engine (combustion temperature ~2500°C, exhaust ~500°C) does not exceed 70-80%, and real efficiency is around 30%.
| η | variable | Thermodynamic efficiency — efficiency |
| T_c | variable | Temperature of the cold reservoir — temperature kelvin |
| T_h | variable | Temperature of the hot reservoir — temperature kelvin |







