substance

Ammonia

Ammonia is a chemical compound of nitrogen and hydrogen that serves as a key solvent and potential biosignature in planetary science.
4 related articles

Description

Ammonia is a pungent gas that smells of 'sal ammoniac' in everyday life. In space, complex molecules are built from it, and on Earth it is needed for fertilizers. Its molecule resembles a pyramid of nitrogen with three hydrogens on top.

History

Although ammonia was known to the ancient Egyptians in the form of sal ammoniac (NH₄Cl) from camel dung, gaseous ammonia was first isolated by Joseph Priestley in 1774, who called it 'alkaline air'. Its composition was determined by Claude Berthollet in 1785. In astrophysics, the first reliable detection of interstellar ammonia was made in 1968 by the group of Cheung and Welch via the inversion transition at 23.7 GHz in the direction of the Galactic center. This discovery confirmed the existence of dense molecular clouds. The spectroscopic parameters of ammonia were later refined in laboratory experiments.

How it works

Ammonia exhibits the quantum effect of inversion—tunneling of the nitrogen atom through the plane of the three hydrogens. The potential curve of the molecule has two minima separated by a barrier of ~2020 cm⁻¹. The tunneling splitting frequency of the ground vibrational state is 23.7 GHz (1.26 cm), which is used in astronomical observations. Inversion transitions are sensitive to gas temperature and density, making ammonia a thermometer for molecular clouds. In the interstellar medium, ammonia is formed mainly on the surface of dust grains by sequential hydrogenation of nitrogen. In planetary atmospheres, it participates in cycles, forming clouds (on Jupiter and Saturn) and contributing to coloration. Symmetric and asymmetric bending modes lie in the infrared region (950–1100 cm⁻¹). For astrophysics, rotational and inversion-rotational transitions in the microwave range are important. Spectroscopically, ammonia is described by quantum numbers J, K, where K is the projection of the angular momentum on the symmetry axis.

Fun fact

In Jupiter's clouds, ammonia creates brown and white bands.

Concept graph →

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