Bragg's law describes the angles at which X-rays diffract from crystal lattices, revealing atomic structure.Stair steps and stride length. If the stride matches the step height, climbing goes smoothly. Similarly, X-rays reflect off atomic layers of a crystal — the reflected waves reinforce each other when the path difference is a multiple of the wavelength. In other words, to 'detect' a maximum, two rays that have traveled different distances must arrive in phase.
The law was first formulated by William Lawrence Bragg in November 1912 (Cambridge) based on experiments with X-ray diffraction on zinc sulfide crystals. Independently and almost simultaneously, Russian crystallographer Georgy Wulf arrived at the same result (1913). For this work, William Henry Bragg and William Lawrence Bragg received the Nobel Prize in Physics (1915) — the only case where a father and son shared the prize.
Used in X-ray, neutron, and electron diffraction to determine the atomic structure of crystals. The method allows deciphering complex molecular architectures — from simple salts to ribosomes. Limits of applicability: work with single crystals, the radiation wavelength must be comparable to interatomic distances; with very strong lattice distortions, the law transitions to a more general dynamic theory of diffraction.
Bragg's law allows measuring distances between atoms with an accuracy of tenths of a nanometer — this is how the double helix of DNA was determined.
| d | variable | Interplanar spacing of the crystal lattice — lattice spacing metre |
| θ | variable | Glancing angle of incidence (and reflection) relative to the planes — angle radian |
| n | variable | Order of reflection (positive integer) — diffraction order |
| λ | variable | Wavelength of the incident wave — wavelength metre |
| sin | operator | Trigonometric sine of the angle — sine function |




