law

Bragg's law

Bragg's law describes the angles at which X-rays diffract from crystal lattices, revealing atomic structure.
8 related articles · 1 formulas · 1 who worked here

Description

Stair steps and stride length. If the stride matches the step height, climbing goes smoothly. Similarly, X-rays reflect off atomic layers of a crystal — the reflected waves reinforce each other when the path difference is a multiple of the wavelength. In other words, to 'detect' a maximum, two rays that have traveled different distances must arrive in phase.

History

The law was first formulated by William Lawrence Bragg in November 1912 (Cambridge) based on experiments with X-ray diffraction on zinc sulfide crystals. Independently and almost simultaneously, Russian crystallographer Georgy Wulf arrived at the same result (1913). For this work, William Henry Bragg and William Lawrence Bragg received the Nobel Prize in Physics (1915) — the only case where a father and son shared the prize.

How it works

Used in X-ray, neutron, and electron diffraction to determine the atomic structure of crystals. The method allows deciphering complex molecular architectures — from simple salts to ribosomes. Limits of applicability: work with single crystals, the radiation wavelength must be comparable to interatomic distances; with very strong lattice distortions, the law transitions to a more general dynamic theory of diffraction.

Fun fact

Bragg's law allows measuring distances between atoms with an accuracy of tenths of a nanometer — this is how the double helix of DNA was determined.

Concept graph →

Formulas

$$2d \sin\theta = n\lambda$$
Constructive interference occurs when path difference equals integer wavelengths.
What is in the formula
dvariableInterplanar spacing of the crystal lattice — lattice spacing metre
θvariableGlancing angle of incidence (and reflection) relative to the planes — angle radian
nvariableOrder of reflection (positive integer) — diffraction order
λvariableWavelength of the incident wave — wavelength metre
sinoperatorTrigonometric sine of the angle — sine function
2d\sinθ=nλ · 2508.10748
nλ=2d\sinθ · 2607.03465

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