Rutherford scattering is the deflection of charged particles by atomic nuclei, governed by Bragg's law.Ernest Rutherford, skeptical of the complex structure of the atom, tasked Hans Geiger and Ernest Marsden with bombarding gold foil with alpha particles. Everyone expected the particles to pass through, only slightly scattering. But Marsden noticed: about one in 8000 particles bounced back! Rutherford was amazed and later compared it to a 15-inch shell ricocheting off tissue paper. He realized that almost all the mass of the atom is concentrated in a tiny nucleus. In 1911, he derived a formula relating the number of scattered particles to angle, energy, and nuclear charge. This was a purely classical result, perfectly explaining the experiment; only later were quantum corrections needed for light nuclei.
Analyzing the experiments of Geiger and Marsden (1909–1911), Rutherford concluded that the atom contains a positively charged nucleus with a radius of ~10⁻¹⁵ m, concentrating almost all the mass. He derived the formula for elastic scattering in the field of a central force 1/r², which ideally matched the data. This disproved Thomson's model ('plum pudding'). Subsequently, the formula became the basis of Rutherford backscattering spectrometry (RBS) for non-destructive analysis of the composition and thickness of thin films.
The formula works for energies from a few keV to several MeV; at lower energies, electron screening is significant, at higher energies, relativistic effects. For 5 MeV alpha particles on gold, it works excellently. The cross-section integral diverges at small angles due to the long-range nature, so in practice a minimum scattering angle is introduced. At very small impact parameters, nuclear forces come into play.
With its help Rutherford discovered the atomic nucleus, and today the method of Rutherford backscattering controls the thickness and composition of nanofilms in microchips.
Rutherford recalled: 'I did not believe in backscattering until Geiger showed me the counter. Then I realized we had hit upon the nucleus.'
| t | variable | elapsed time — time second |
| λ | variable | decay constant — decay constant per second |
| N_0 | variable | initial number of radioactive nuclei — number of nuclei |
| N | variable | current number of radioactive nuclei — number of nuclei |
| ln | operator | natural logarithm of the ratio — natural logarithm |
| \Delta\theta | variable | Standard deviation of the estimator for parameter theta — standard deviation |
| \mathcal{F}(\rho_\th | variable | Quantum Fisher information of the state rho_theta — quantum fisher information |
| p_m | variable | observed polarization degree — polarization degree |
| p_0 | variable | intrinsic polarization degree (without Faraday effects) — polarization degree |
| σ_RM | variable | dispersion of rotation measure along the line of sight — rotation measure dispersion radian per square metre |
| λ | variable | wavelength of radiation — wavelength metre |
| exp | operator | exponential function — exponential |



