The distribution of light frequencies emitted by a system, revealing internal dynamics and decay properties.An emission spectrum is the set of frequencies of electromagnetic radiation emitted by a system, typically atoms or molecules, when they transition from higher to lower energy states. Each element or compound has a unique emission spectrum, often appearing as discrete bright lines on a dark background. This spectrum reveals the internal energy-level structure of the emitting species and provides information about its composition, temperature, and motion.
The study of emission spectra began in the 19th century with the work of Robert Bunsen and Gustav Kirchhoff, who established that each element has a unique spectral fingerprint. The theoretical explanation was provided by Niels Bohr's model of the hydrogen atom in 1913.
When an electron in an atom absorbs energy, it jumps to a higher energy level. When it falls back to a lower level, it emits a photon with energy equal to the difference between the two levels. The frequency of the photon is determined by Planck's relation, E = hν. The collection of all possible transitions produces the characteristic emission lines of the element.
Emission spectra are used in spectroscopy to identify chemical elements in stars, gases, and materials. They are also employed in flame tests, laser design, and environmental monitoring.
The emission spectrum of hydrogen, known as the Balmer series, was the first to be explained by quantum theory, and its precise wavelengths are still used to calibrate spectrometers today.


