
An exoplanet atmosphere is the gaseous envelope surrounding a planet outside our solar system.The main method is transmission spectroscopy: during transit (the planet passing across the star's disk), some starlight is filtered through the upper layers of the atmosphere. Atoms and molecules absorb radiation at characteristic wavelengths, creating a spectral fingerprint. From this, the presence of water vapor, carbon dioxide, methane, as well as temperature and pressure can be determined.
The first successful analysis of an exoplanet atmosphere was performed by David Charbonneau's group in 2001 using the STIS spectrograph on the Hubble telescope. Sodium at 589 nm was detected on planet HD 209458 b. Later, the Spitzer infrared telescope and the Kepler space observatory led by William Borucki enabled statistical studies of hundreds of hot Jupiters. With the launch of JWST, the era of detailed chemical analysis of Earth-like planet atmospheres began.
During transit, the fraction of radiation blocked by the planet is (R_p/R_s)^2, and the thin atmospheric shell adds about 2R_p·h/R_s^2 to the absorption, where h is the effective height of the atmosphere. This height is given by the scale height H = kT/(μg), where k is Boltzmann's constant, T is temperature, μ is mean molecular mass, and g is gravitational acceleration. Absorption at specific wavelengths follows the Bouguer–Lambert–Beer law; the depth of spectral lines reflects the abundance of the corresponding chemical elements. Light curves at different wavelengths are recorded photometrically, and spectral resolution allows identification of molecular bands of H₂O, CO, CO₂, CH₄, etc.
Searching for signs of life and assessing planetary habitability by detecting water, oxygen, or methane in the atmospheric spectrum.
On exoplanet KELT-9b, the dayside is heated to 4600 K — hotter than many stars — and iron and titanium vapors float in its atmosphere.




























