A quantum dot is a nanoscale semiconductor structure that confines electrons and holes in three dimensions.A quantum dot is a semiconductor nanocrystal typically 2 to 10 nm in size, in which the motion of charge carriers (electrons and holes) is confined in all three dimensions, leading to quantization of the energy spectrum. Due to spatial confinement, energy levels become discrete, like atomic ones, and depend on the dot's size. Optical transitions between these levels yield narrow luminescence bands. The emission color can be continuously tuned by changing the nanocrystal diameter.
In 1981, Alexey Ekimov, while studying CuCl nanocrystals in silicate glass, noticed a blue shift of the absorption edge upon decreasing crystal size. In 1983-84, Louis Brus theoretically substantiated the quantum size effect in semiconductor nanocrystals, demonstrating the relationship between transition energy and particle radius. In 1993, Moungi Bawendi and colleagues developed a method for high-temperature synthesis of monodisperse CdSe quantum dots, paving the way for practical use. Subsequent research led to the creation of cadmium-free dots and applications in bioimaging and optoelectronics.
Quantum confinement: when the crystal size becomes smaller than the exciton Bohr radius, the motion of charge carriers is quantized. The Schrödinger equation for a particle in a three-dimensional potential well yields discrete energy levels, with spacing increasing as size decreases. Absorption of a photon creates an exciton, which then recombines radiatively. Due to the size dependence of the transition energy, quantum dots of the same composition can emit across the entire visible range. Spectral homogeneity is limited by the size dispersion of the ensemble, and blinking is associated with Auger ionization processes.
Quantum dots are used in QLED displays for bright and pure colors, and also in biomedicine as luminous markers for tracking cells.
Quantum dots are so bright and stable that they are used to create TVs with record color gamut, and in biology to track the movement of a single molecule inside a living cell.























