concept

quantum number

A quantum number is a discrete value that characterizes a quantum state, such as spin or charge, in physical systems.
8 related articles · 4 formulas · 1 who worked here

Description

Electrons in an atom are like birds in a tree. Each bird occupies its own branch, at a certain height and with a certain flight direction. Quantum numbers are a precise description of the place: which branch (energy), from which side (orbital shape), in which nest (magnetic number), and which way it's facing (spin). No two addresses are the same.

History

The idea of quantum numbers originated in Bohr's atomic model (1913) with the introduction of the principal number n. Arnold Sommerfeld generalized the model in 1916, adding orbital and magnetic numbers to explain fine structure. A decisive contribution was made by Wolfgang Pauli, who proposed spin and the exclusion principle in 1925. Erwin Schrödinger created wave mechanics in 1926, where the numbers n, l, mₗ received a rigorous interpretation as eigenvalues of operators, and the Dirac equation (1928) gave spin a relativistic foundation.

How it works

The wave function of an electron is determined from the Schrödinger equation. When separating variables in a central potential, quantum conditions arise: the radial equation gives n = 1, 2, 3…, the angular one gives l = 0, …, n−1 and mₗ = −l, …, l. Spin is introduced via the Dirac equation and for the electron takes values s=1/2, mₛ = ±1/2. The Pauli principle forbids two electrons from occupying the same quantum state, which explains the sequential filling of shells and the periodicity of chemical properties. Thus, quantum numbers are a direct consequence of the Schrödinger equation and the Pauli principle.

Fun fact

The spin quantum number of an electron takes only two values: +1/2 or -1/2, like a coin that always lands heads or tails, but never on its edge. It is precisely thanks to the Pauli principle, which forbids identical sets of numbers, that atoms do not collapse and form all the variety of elements.

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Formulas

$$D(\psi_1, \psi_2) = \sqrt{1 - |\langle\psi_1|\psi_2\rangle|^2}$$
Distance between quantum states based on their overlap.
What is in the formula
Dvariabledistance between quantum states — quantum distance
ψ1variablefirst quantum state — wave function
ψ2variablesecond quantum state — wave function
⟨ψ1|ψ2⟩operatorcomputes the complex amplitude of one state in another — inner product
|·|operatorgives the magnitude of the complex amplitude — absolute value
√operatortakes the non-negative root — square root
t(|ψ_1\rangle,|ψ_2\rangle)=\sqrt{1-|\langleψ_1|ψ_2\rangle|^2} · 2505.00777v1
$$\operatorname{Tr}[A\rho]$$
The expectation value of operator A in quantum state ρ.
What is in the formula
AvariableOperator whose expectation is taken — operator
ρvariableDensity matrix (quantum state) — density matrix
TroperatorComputes the sum of diagonal elements of a matrix — trace operator
\operatorname{tr}[\varphi(h(θ))ρ] · 2607.05000
$$E_n = \hbar\omega (n + \tfrac{1}{2})$$
Energy levels of a quantum harmonic oscillator.
What is in the formula
E_nvariableEnergy of the nth level — energy joule
nvariableQuantum number (non-negative integer) — quantum number
\hbarconstantReduced Planck constant — reduced planck constant = 1.054571817e-34 joule second
\omegaconstantAngular frequency of the oscillator — angular frequency radian per second
$$\oint p \, dq = n h$$
Quantization condition for action integrals in old quantum theory.
What is in the formula
pvariablecanonical momentum — momentum kilogram metre per second
qvariablecanonical coordinate — position metre
nvariablequantum number (integer) — quantum number
hconstantfundamental constant relating energy to frequency — planck constant = 6.62607015e-34 joule second
∮operatorintegral over one full period of the motion — closed line integral

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