A quantum number is a discrete value that characterizes a quantum state, such as spin or charge, in physical systems.Electrons in an atom are like birds in a tree. Each bird occupies its own branch, at a certain height and with a certain flight direction. Quantum numbers are a precise description of the place: which branch (energy), from which side (orbital shape), in which nest (magnetic number), and which way it's facing (spin). No two addresses are the same.
The idea of quantum numbers originated in Bohr's atomic model (1913) with the introduction of the principal number n. Arnold Sommerfeld generalized the model in 1916, adding orbital and magnetic numbers to explain fine structure. A decisive contribution was made by Wolfgang Pauli, who proposed spin and the exclusion principle in 1925. Erwin Schrödinger created wave mechanics in 1926, where the numbers n, l, mₗ received a rigorous interpretation as eigenvalues of operators, and the Dirac equation (1928) gave spin a relativistic foundation.
The wave function of an electron is determined from the Schrödinger equation. When separating variables in a central potential, quantum conditions arise: the radial equation gives n = 1, 2, 3…, the angular one gives l = 0, …, n−1 and mₗ = −l, …, l. Spin is introduced via the Dirac equation and for the electron takes values s=1/2, mₛ = ±1/2. The Pauli principle forbids two electrons from occupying the same quantum state, which explains the sequential filling of shells and the periodicity of chemical properties. Thus, quantum numbers are a direct consequence of the Schrödinger equation and the Pauli principle.
The spin quantum number of an electron takes only two values: +1/2 or -1/2, like a coin that always lands heads or tails, but never on its edge. It is precisely thanks to the Pauli principle, which forbids identical sets of numbers, that atoms do not collapse and form all the variety of elements.
| D | variable | distance between quantum states — quantum distance |
| ψ1 | variable | first quantum state — wave function |
| ψ2 | variable | second quantum state — wave function |
| ⟨ψ1|ψ2⟩ | operator | computes the complex amplitude of one state in another — inner product |
| |·| | operator | gives the magnitude of the complex amplitude — absolute value |
| √ | operator | takes the non-negative root — square root |
| A | variable | Operator whose expectation is taken — operator |
| ρ | variable | Density matrix (quantum state) — density matrix |
| Tr | operator | Computes the sum of diagonal elements of a matrix — trace operator |
| E_n | variable | Energy of the nth level — energy joule |
| n | variable | Quantum number (non-negative integer) — quantum number |
| \hbar | constant | Reduced Planck constant — reduced planck constant = 1.054571817e-34 joule second |
| \omega | constant | Angular frequency of the oscillator — angular frequency radian per second |
| p | variable | canonical momentum — momentum kilogram metre per second |
| q | variable | canonical coordinate — position metre |
| n | variable | quantum number (integer) — quantum number |
| h | constant | fundamental constant relating energy to frequency — planck constant = 6.62607015e-34 joule second |
| ∮ | operator | integral over one full period of the motion — closed line integral |
















