Complex molecules form in space through processes like shock chemistry and ice-phase reactions.Astrochemical molecular formation refers to the processes by which complex molecules are created in space, from simple diatomic species to large organic compounds. These molecules form in a variety of environments, including interstellar clouds, circumstellar envelopes, and planetary atmospheres. The chemistry is driven by gas-phase reactions, grain-surface reactions, and shock-induced chemistry, often involving icy mantles on dust grains.
The field began in the 1930s with the detection of simple molecules like CH and CN in interstellar space, but the importance of grain-surface chemistry was recognized later, in the 1970s and 1980s.
In cold interstellar clouds, atoms and simple molecules stick to dust grains, forming icy layers. Ultraviolet radiation and cosmic rays can drive reactions within these ices, producing more complex molecules. When a shock wave passes through the cloud, it can sputter or evaporate the ices, releasing the newly formed molecules into the gas phase, where they can be detected by their rotational emission lines. Grain-surface reactions are particularly efficient for hydrogenation and other simple additions.
Understanding molecular formation is crucial for interpreting astronomical observations, studying star formation, and investigating the origins of prebiotic molecules in space.
More than 200 different molecules have been detected in the interstellar medium, including complex organic species like ethyl formate, which smells like raspberries.






