Permittivity is a material property that quantifies how an electric field affects and is affected by a dielectric medium, influencing charge interactions and electronic behavior.Dielectric permittivity (ε) characterizes the ability of a medium to polarize under an electric field and weaken it. In vacuum, the electric constant ε₀ ≈ 8.85·10⁻¹² F/m. The relative permittivity εᵣ = ε/ε₀ shows how many times weaker the interaction of charges in the medium is compared to vacuum. For water, εᵣ ≈ 80, which explains water's high dissolving power for ionic compounds.
Ideas about dielectric permittivity date back to Henry Cavendish's experiments (late 18th century) and systematic studies by Michael Faraday (1837), who introduced the concept of 'specific inductive capacity'. The term 'dielectric permittivity' was proposed by William Thomson in 1845. James Clerk Maxwell (1862) mathematically linked ε and the speed of light c = 1/√(ε₀μ₀), demonstrating the electromagnetic nature of light. Later developments in quantum theory of polarizability (by Hans Bethe, Lars Onsager) allowed computation of ε from molecular properties.
An applied electric field E causes displacement of charges in the dielectric: electron shells deform (electronic polarization), ionic lattices shift (ionic polarization), permanent dipoles orient (orientational polarization). Each mechanism creates a dipole moment, and the macroscopic polarization P is the sum of moments per unit volume. Dielectric permittivity ε relates electric displacement D = ε₀E + P = ε₀εᵣE. In alternating fields, a phase shift occurs between displacement and field, leading to dielectric losses. The Lorentz oscillator model or the Debye relaxation model is used for description.
A capacitor in electronics stores charge better the higher the dielectric permittivity of the insulator between the plates; without it, smartphones would be the size of a suitcase.
Thanks to the huge dielectric permittivity of water (about 80 at room temperature), table salt readily dissolves into ions — water seems to pull the ions apart, weakening their bond by a factor of 80.











