
A method that analyzes starlight filtered through a planet's atmosphere to identify its chemical composition.Transit spectroscopy is a technique for studying the atmospheres of exoplanets — planets orbiting stars other than the Sun. When a planet passes directly between its host star and an observer on Earth, a small fraction of the starlight is filtered through the planet's atmosphere before reaching our telescopes. By analyzing this filtered light, astronomers can identify which molecules are present in the atmosphere, because different chemicals absorb light at specific, characteristic wavelengths.
The first detection of an exoplanet atmosphere using transit spectroscopy was reported in 2001 by David Charbonneau and collaborators, who observed the star HD 209458 and found sodium absorption in the atmosphere of its hot Jupiter planet.
During a transit, the planet blocks a tiny portion of the star's light, causing a slight dip in brightness. But the atmosphere itself also absorbs some additional light at particular wavelengths, creating subtle variations in the depth of that dip depending on the wavelength. By comparing the spectrum of the star during the transit with its spectrum outside the transit, scientists can isolate the atmospheric absorption signature. This reveals the chemical composition, temperature structure, and even the presence of clouds or hazes in the planet's atmosphere.
Transit spectroscopy is the primary method used to characterize exoplanet atmospheres, including the search for potential biosignature gases like oxygen and methane in Earth-like planets, and it is a key observational mode for space telescopes like Hubble, James Webb, and future missions such as Ariel.
The same technique has been used to detect sulfur compounds in exoplanet atmospheres, which can reveal information about the planet's formation history and internal processes.












