The emission of light by a substance that has absorbed light or other electromagnetic radiation.Fluorescence is the process by which a substance absorbs light or other electromagnetic radiation and then re-emits it almost immediately, at a longer wavelength. This is a form of photoluminescence, distinct from phosphorescence, where the re-emission is delayed. The phenomenon is ubiquitous in nature and technology, from the glow of certain minerals under ultraviolet light to the functioning of modern biological imaging and LED lighting. It occurs when an electron is excited to a higher energy state and then relaxes back to its ground state, releasing the excess energy as a photon.
The term 'fluorescence' was coined in 1852 by George Gabriel Stokes, who observed that the mineral fluorspar (calcium fluoride) emitted visible light when illuminated by ultraviolet radiation. He also formulated Stokes' law, which states that the emitted light has a longer wavelength than the absorbed light.
When a photon strikes a molecule or atom, its energy can be absorbed, promoting an electron to a higher orbital. This excited state is unstable; the electron quickly loses some energy through vibrations or heat (a process called internal conversion) and then falls back to the ground state, emitting a photon with lower energy and thus longer wavelength than the absorbed one. This entire process typically takes nanoseconds, which is why fluorescence stops almost instantly when the excitation source is removed.
Fluorescence is used in fluorescent lamps, biological and medical imaging (e.g., fluorescent tags for microscopy), and in materials science to study the properties of semiconductors and crystals, as referenced in the article about perovskite crystals absorbing light in reverse.
Some deep-sea fish use fluorescence to convert blue light into green or red light, which helps them communicate in an environment where most light is filtered out.




