
An electron emitted from a material when it absorbs a photon.A photoelectron is an electron ejected from a material when it absorbs a photon. This phenomenon, known as the photoelectric effect, was explained by Einstein in 1905 and provided crucial evidence for the quantum nature of light. Photoelectrons carry information about the energy levels of electrons in the material, making them a powerful probe of electronic structure.
Heinrich Hertz observed the effect in 1887, but Albert Einstein explained it in 1905 using the concept of light quanta, for which he received the Nobel Prize in 1921.
When a photon strikes an atom or solid, its energy can be transferred to an electron. If the photon's energy exceeds the material's work function (the minimum energy needed to free an electron), the electron escapes with kinetic energy equal to the photon energy minus the binding energy. By measuring the kinetic energy and angle of emitted photoelectrons, scientists can map out the electronic band structure of materials.
Photoelectron spectroscopy is a standard technique in materials science and surface chemistry, used to analyze the composition and electronic states of surfaces, including in semiconductor development and catalysis research.
The photoelectric effect is what powers solar panels — each photon that knocks out an electron contributes to the electric current.



















