The emission of light from a material after it absorbs photons, often revealing its composition.Photoluminescence is the emission of light from a material after it absorbs photons, a process that often reveals the material's composition and electronic structure. When a photon is absorbed, it excites an electron to a higher energy state; when the electron returns to its ground state, it may emit a photon of lower energy. This phenomenon is widely used in science and technology to probe materials, from semiconductors to biological tissues, because the emitted light carries information about energy levels, defects, and impurities.
The phenomenon was first observed in the 19th century, with George Stokes describing the wavelength shift in 1852, coining the term 'fluorescence'. The broader concept of photoluminescence was later formalized as quantum mechanics explained the underlying energy transitions.
The mechanism involves three steps: absorption of a photon, excitation of an electron to a higher energy level, and subsequent relaxation with emission of a photon. The emitted photon's energy is typically lower than the absorbed one due to non-radiative losses, a shift known as the Stokes shift. In materials like quantum dots or perovskites, the emission wavelength can be tuned by size or composition, making photoluminescence a sensitive probe of quantum confinement and band structure.
Photoluminescence is used in LED lighting, fluorescent microscopy for biological imaging, and in quality control of semiconductors, as well as in advanced techniques like quantum-correlated spectroscopy for detecting microplastics.
Some deep-sea fish use photoluminescence to communicate in the dark, producing light through chemical reactions rather than absorption, but the principle of light emission is similar.










