First Confident SiO Signal in the Atmosphere of a Directly Imaged Companion TWA5B: A Key to Refractory Material and Clouds ✛ ✦

Original: "The CRIMSON survey I: super-stellar SiO in the directly imaged companion TWA 5 B from high-resolution M-band spectroscopy"
arXiv:2606.03824v1 · 2026-06-02 · CC BY 4.0 · 4 min
High-resolution M-band spectroscopy has detected gaseous silicon monoxide in the young super-Jupiter TWA5B, revealing its refractory composition and the absence of silicate clouds.

Context

Direct imaging of giant exoplanets offers a unique window into their chemical makeup and formation history. Refractory elements like silicon, which existed in solid form in the protoplanetary disk, are of particular interest as they trace the amount of accreted silicates. Until recently, however, detecting refractory compounds in the atmospheres of directly imaged planets was challenging due to low contrast and cloud screening. The new CRIMSON survey with CRIRES+ on the VLT exploits the M-band (3.5–5.2 µm) to hunt for spectral lines of molecular SiO — the main carrier of gaseous silicon in hot atmospheres. This approach offers a direct estimate of solid enrichment and simultaneously diagnoses the presence of silicate clouds that can distort observed abundances.

Methods

Observations of the TWA5 system (distance 49.6 pc) were carried out with VLT/CRIRES+ in high spectral resolution mode (R≈92,000) with adaptive optics. The spectrograph slit was oriented to simultaneously capture light from the central binary star (M1.5) and the companion TWA5B (M8.5) at an angular separation of 1.8″. To battle strong thermal background and telluric contamination, a special A-B background subtraction procedure and a telluric transmission model built from calibration star observations were applied. After spectral extraction and removal of the dominant host star light using principal component analysis (PCA), cross-correlation with synthetic spectra revealed molecular lines of H2O, CO, and SiO. The model also included opacity from collision-induced absorption of H2–H2 and H2–He. Then, within a Bayesian retrieval using HyDRA, the atmospheric abundances, dynamics, and temperature profile were estimated, with models subjected to the same PCA cleaning as the data to account for its effects.

Results

In the spectrum of TWA5B, three molecules were confidently detected: H2O (SNR=18.8), CO (SNR=9.1), and SiO (SNR=7.5). The detection of SiO stands out — the first robust evidence of gaseous silicon in a directly imaged companion. The SiO abundance was log(VMR)=–3.56, corresponding to nearly all silicon being in the gas phase at pressures near 1 bar. The retrieval also indicated low cloud opacity and a deep cloud base, ruling out significant condensation of magnesium-silicate dust in the observed region. The measured Si/H ratio was ~25 times higher than stellar ([Si/H]★=1.41), pointing to strong atmospheric enrichment with refractory material. The C/O=0.26, O/Si≈9.6, and C/Si≈2.4 ratios fall within the range consistent with accretion beyond the CO snowline or gravitational instability with subsequent solid capture.

Implications

Observing SiO in the M-band provides a fundamentally new tool for studying the chemistry of refractory elements in exoplanets. Since SiO is the dominant gaseous carrier of silicon in hot, cloud-free atmospheres, its abundance directly reflects the primordial mass of silicates captured during formation. This breaks the degeneracy inherent in the C/O ratio alone and allows a more precise reconstruction of a planet’s birthplace in the disk. Moreover, the dependence of SiO abundance on silicate condensation turns it into a sensitive indicator of cloud types (MgSiO3, Mg2SiO4, SiO2) and their formation conditions. In the future, such measurements can be extended to the entire population of hot Jupiters and isolated brown dwarfs, creating a condensation map as a function of temperature.

Future development

The CRIRES+ M-band methodology will be applied to other targets in the CRIMSON survey (including β Pic b and HR 3549 b), enabling the tracking of SiO abundance evolution from 2400 K down to 1200 K. Combined with archival K-band data, this will paint a full picture of changes in C/O, volatile-to-refractory ratios, and isotopic composition for each companion. Future instruments, such as METIS on the ELT, will provide even higher quality spectra in the L and M bands, while space observatories (JWST) will offer additional information on silicate dust in the mid-infrared. Joint analysis of SiO and dust feature data will refine models of cloud particle growth and settling, including kinetic nucleation effects.

Impact

The work will impact observational exoplanet astrophysics (development of high-resolution methods in the thermal infrared), planet formation theory (constraints on solid accretion), and atmospheric modeling (cloud diagnostics and non-equilibrium chemistry).

Next steps

Expand the sample to cooler objects where silicate clouds are expected to appear, and compare SiO measurements with infrared dust excesses obtained by JWST/MIRI.

Key open problems

The detection of SiO links the problem of giant planet formation (specifically, mechanisms of solid accretion in disks) with the task of determining cloud composition in sub-stellar atmospheres. It is also a step toward resolving how condensation of refractory elements distorts observed volatile abundances, which directly affects the interpretation of key C/O and metallicity ratios.

The knowledge machine's view

This section is addressed to the author of the paper and their colleagues. Neighbouring works were found by meaning-based search across our archive, not by word overlap. We do not review: we show the field around the work.

What the work does

This study reports the first robust detection of SiO in the atmosphere of the directly imaged companion TWA 5B, based on VLT/CRIRES+ data in the M band. Using cross-correlation and Bayesian retrieval, we estimated the abundances of H2O, CO, and SiO, as well as cloud properties and the temperature profile. We find strong silicon enrichment ([Si/H]★ = 1.41) and low cloud opacity, pointing to the accretion of refractory material.

Where its strength is

Detecting SiO provides direct access to gaseous silicon in cold companions, where it is usually locked up in dust, and allows us to estimate solid enrichment without model-dependent assumptions about condensation.

Where it could go next

Worth trying

  • Use SiO lines as a tracer of convective penetration depth and mixing in the atmospheres of directly imaged planets.
  • Perform a joint retrieval of SiO and cloud parameters for a sample of companions to calibrate the relationship between gaseous silicon and dust opacity.
  • Compare the Si/H ratio with predictions from planetesimal accretion models for different host masses and planetary orbital distances.

Why this may matter

Such measurements directly link atmospheric composition to the accretion history of solids, which is critical for testing theories of giant planet formation.

Original abstract

as written by the authors arXiv:2606.03824v1

Silicon is a key refractory element in giant planet atmospheres, which governs the formation of magnesium-silicate clouds, and reflects the quantity of silicates accreted during formation. While observations of directly imaged giant exoplanets have focused on the measurement of volatile species (e.g. CO, H$$_2$$O), high-resolution spectroscopy with CRIRES+ M-band provides access to gas phase silicon chemistry in sub-stellar atmospheres, through the ro-vibrational band head of SiO at 4 $$\mu$$m. Here, we present the first results of the CRIMSON survey of silicon chemistry in directly imaged companions with CRIRES+ M-band. We report the strong detection of gaseous SiO (S/N = 7.5) in the directly imaged companion TWA 5 B, with an atmospheric abundance of log(SiO) = $$-3.56^{+0.42}_{-0.32}$$ VMR, providing access to the refractory content of the atmosphere. The high retrieved SiO abundance implies the absence of significant magnesium-silicate cloud condensation, and thus the atmospheric silicon abundance is contained almost entirely within the observed gas phase SiO. Using the detection of refractory silicon, together with strong detections of the volatile species CO (S/N = 9.1) and H$$_2$$O (S/N = 18.8), we measure a stellar C/O and a marginally sub-stellar O/Si and C/Si, but a super-stellar Si/H ([Si/H]$$_{\star}$$ = $$1.41^{+0.42}_{-0.32}$$). Collectively, these volatile-to-refractory ratios are consistent with formation through core-accretion beyond the CO snowline, or gravitational instability followed by substantial solid enrichment. Finally, we discuss how gas phase SiO provides a unique diagnostic of the cloud properties in hot gas-giants, and can be used to probe the dominant cloud species forming across the directly imaged planet and isolated brown dwarf populations.

Silicon monoxide (SiO) is a molecule that in the gas phase occurs not only in the atmospheres of hot exoplanets but also in the interstellar medium, where it forms in supernova shock waves. However, under Earth conditions, SiO rapidly polymerizes into solid silicates — the very stuff ordinary sand is made of.

Key numbers

  • SiO signal-to-noise ratio: 7.5
  • H2O signal-to-noise ratio: 18.8
  • TWA5B temperature: ~2400 K
  • Si/H enrichment over stellar: [Si/H]★ = 1.41 (~25 times)
  • TWA5B mass: 25 ± 5 Jupiter masses
Scientists
Christian DopplerD. B. McLaughlinDidier QuelozMichel MayorR. A. RossiterDavid Charbonneau
Concepts
titanium oxide silicon carbide carbon to oxygen ratio silicon carbon monoxide sulfur dioxide titan gas cloud sodium gas dust young stellar object glycine chemical galactic archaeology mantle rocky planet magnesium cosmic dust analysis galactic halo cloud