substance

olivine

A common mantle mineral into which wadsleyite transforms as pressure decreases during upwelling.
14 related articles

Description

Olivine is a magnesium-iron silicate mineral that is the most abundant mineral in Earth's upper mantle, down to about 410 kilometers depth. It is the primary constituent of the rock peridotite, which makes up the bulk of the mantle. When mantle material rises toward the surface, it undergoes a phase transition: at lower pressures, olivine is stable, but at greater depths it transforms into denser minerals like wadsleyite and ringwoodite. This transformation is not just a mineralogical curiosity—it plays a key role in plate tectonics, mantle convection, and the behavior of seismic waves passing through the Earth.

History

Olivine has been known since antiquity as the gemstone peridot, but its role as a major mantle mineral was established in the early 20th century through petrological studies. The specific phase transition to wadsleyite was identified in the 1960s by experimental petrologists such as A.E. Ringwood, who synthesized the high-pressure polymorphs and linked them to seismic discontinuities.

How it works

Olivine has an orthorhombic crystal structure with isolated silica tetrahedra linked by magnesium or iron ions. At high pressure (around 13–14 GPa, corresponding to ~410 km depth), the structure collapses into the more compact spinel-like structure of wadsleyite, which has a higher density. This phase change is exothermic, meaning it releases heat, and it occurs over a narrow depth range, creating a sharp seismic reflector. During upwelling, the reverse transformation from wadsleyite to olivine absorbs heat and can slow or even halt rising mantle plumes, a process that influences volcanic activity at hotspots.

In practice

Olivine is used in foundry sands, as a refractory material, and in carbon capture research, where its weathering can sequester CO2. In geophysics, its phase behavior is essential for interpreting seismic tomography and modeling mantle dynamics.

Fun fact

Olivine is also found in meteorites and on Mars, where it can indicate past water activity because it alters to iddingsite in the presence of liquid water.

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