substance

calcium

A chemical element that is part of the oxygen-evolving complex, playing a structural and functional role.
15 related articles

Description

Calcium is a chemical element (symbol Ca, atomic number 20) that plays a dual role in biology and geochemistry. In the context of photosynthesis, it is an essential component of the oxygen-evolving complex, the enzyme cluster in plants, algae, and cyanobacteria that splits water molecules to release oxygen. Without calcium, this complex cannot assemble or function, making the element indispensable for the oxygen-rich atmosphere we breathe. Beyond biology, calcium is abundant in rocks and minerals, and its presence in cosmic dust and planetary bodies influences the chemical evolution of disks around young stars.

History

Calcium was isolated as an element in 1808 by Humphry Davy through electrolysis of lime. Its role in the oxygen-evolving complex was established in the 1970s–1980s through spectroscopic and biochemical studies, notably by Bessel Kok and others who identified the four-step cycle of water oxidation.

How it works

In the oxygen-evolving complex, calcium sits alongside manganese atoms in a cluster that cycles through oxidation states. The calcium ion (Ca²⁺) provides structural stability and helps orient water molecules for the reaction, though it does not itself undergo redox changes. Its ionic radius and charge allow it to coordinate with amino acid residues and inorganic ligands, holding the cluster together during the high-energy steps of water splitting. In geochemical contexts, calcium's behavior as a cation affects mineral formation and the alkalinity of solutions, as seen in the reversible transformation between calcium hydroxide and calcium carbonate in aqueous environments.

In practice

Calcium is used in artificial photosynthesis research to mimic the oxygen-evolving complex, and in materials science for creating biocompatible ceramics and cements. It is also a key tracer in astrochemistry for studying the composition of protoplanetary disks.

Fun fact

The calcium ion in the oxygen-evolving complex is the only metal ion in that cluster that does not change its oxidation state during the entire water-splitting cycle.

Related articles · 15

A Viscous Film at a Mineral Wall
Two mica plates, smooth as mirrors, slowly approach each other in a calcium solution. At a distance of fifty nanometers, an invisible barrier suddenly appears between them: as if someone had stretched a web of molecules between the walls. This web prevents the plates from touching, even though by all calculations they should glide freely toward each other.
Stellar Palimpsests: How We Read the History of Swallowed Planets
Every star is a living archive, and its spectrum a multilayered manuscript. Over billions of years, the history of the galaxy is written into it: the galactic chemical evolution of the Milky Way leaves a smooth trace in elemental abundances.
Stellar2026-07-023 minarXiv:2607.01699
Galactic Recipe: How the Sun Stopped Being Special
For years, the Sun teased astrophysicists. In its atmosphere, refractory elements, like spices in a basic recipe, were slightly less abundant than in nearly identical twin stars. Suspicion arose: could our star be modest, skipping the planetary "dessert" that others devour with gusto?
q-bio.BM2026-05-191 minarXiv:2605.19252express
The Chemical Signature of Life: How to Find It by Its Elements
From carbon, nitrogen, oxygen, and sulfur, you can assemble 10⁶⁰ different small molecules: that's a 1 with 60 zeros, more than the stars in the visible universe. Life uses only a tiny fraction of this menu, but not randomly.
Materials2026-05-011 minarXiv:2605.01045express
How Water Turns into Alkali and Back
In a crystal of water and caustic cesium, oxygen and cesium atoms sit in place like beads in a rigid lattice. Hydrogen atoms behave differently: they are like passengers constantly changing seats. In this layered material, each oxygen is linked to three neighbors via hydrogen bridges, forming a honeycomb-like pattern.
Exoplanets2026-03-291 minarXiv:2603.27598express
How to find life on other planets: a new method
A chemical detective searches for life on other planets. Its tool is a mass spectrometer that identifies molecules by weight (the same device earthly forensic scientists use to analyze clues).
Chemical Physics2026-03-262 minarXiv:2603.24924express
Hydrogen from Algae: A Green Light for Clean Energy
Conventional solar panels convert light into electricity, but here light splits water into hydrogen and oxygen. Hydrogen is a clean fuel, but the process is slow. To speed it up, helper substances that donate electrons are added. Often this is alcohol, but it's a shame to waste it.
Galaxies2026-02-231 minarXiv:2602.20241express
Chemistry Around Galaxies: What Their Outskirts Breathe
The kitchen of a distant galaxy isn't limited to its bright disk. Around every star system, there's an invisible cloud of gas, like steam above a pot of soup. Astronomers peeked into this steam around galaxies that appear as they were just one and a half billion years after the Big Bang.
Exoplanets2026-02-171 minarXiv:2602.16030express
Cosmic Kitchen: How Carbon and Oxygen Shape the Look of Disks
When a chef prepares a dish, not only the proportions of ingredients matter but also their total amount. Two pies with the same sugar-to-flour ratio but made from different batch sizes will turn out differently. So it is with disks around young stars: carbon and oxygen are the key 'spices,' and their absolute amounts change the look of the cosmic 'kitchen' no less than their ratio.
Exoplanets2026-02-151 minarXiv:2602.14334express
Cosmic Oven: How Heat Baked the Building Blocks of Life on Jupiter's Moons
Life may be hiding in the oceans beneath the ice of Europa, Ganymede, and Callisto. Its carbon-based building blocks perhaps baked before the moons were born — in a disk of gas and dust around a young Jupiter. This giant cosmic oven ran on slow frictional heating, not harsh ultraviolet light.
Materials2026-01-211 minarXiv:2601.14807express
Invisible Holes in a Two-Dimensional Crystal
A crystal one atom thick is like a sheet of paper you can write on with electricity. Such a material promises to become the foundation for tiny, fast microchips. But before putting it into production, you need to know exactly what it's made of. And that's where the usual formula falls apart.
Quantum Physics2026-01-131 minarXiv:2601.09020express
Salt in the Cell Changes the Rules of the Game
In a glass of salty water, even if it sits perfectly still, something is always happening. Tiny salt particles, ions, float and collide, sending ripples through the water. These ripples are invisible, but they create a force that attracts or repels nearby objects. Previously, it was thought that this force only acts over very short distances, as if it quickly fades out.
Materials2026-01-101 minarXiv:2601.06583express
A Chromium Battery That Won't Rust
A piece of chromium exposed to air gets covered in invisible armor, an oxide film, within a minute. That film protects the metal from rust, but for a battery it's a disaster: the film blocks chromium ions, so no current flows. Scientists mixed five metals — chromium, bismuth, copper, tin, and nickel.
q-bio.BM2026-01-092 minarXiv:2601.14273express
Oxygen from Water: How Plants Build It Brick by Brick
In every leaf, in the light, a factory works that splits water into oxygen and hydrogen. The oxygen goes into the air we breathe, and the plant uses the hydrogen for food. The heart of this factory is a protein complex with four manganese atoms and one calcium atom.
Exoplanets2025-11-241 minarXiv:2511.19112express
Rusty Heart of an Interstellar Comet Makes It Shine
The second interstellar guest, comet 3I/ATLAS, shines unusually due to rusting metal grains in its icy core. As it gets closer to the Sun, it behaves like an old tin can tossed into a fire: the heat melts the ice, water seeps into the metal, and vigorous corrosion begins.