principle

Bose–Einstein statistics

Bose-Einstein statistics is a quantum principle describing the distribution of bosons over energy states, allowing multiple particles in the same state.
40 related articles · 1 formulas · 2 who worked here

Description

In 1924, the young Indian physicist Satyendra Nath Bose sent Albert Einstein his derivation of Planck's radiation law, treating photons as indistinguishable particles. Einstein immediately saw the universality of the approach and in 1925 generalized it to any massive particles with integer spin. Thus Bose–Einstein statistics was born. Unlike classical physics, where particles can be labeled, in the quantum world identical bosons are fundamentally indistinguishable, and their energy distribution is described by a formula: the average number of particles in a state with a given energy depends on the ratio of the energy difference and chemical potential to the thermal energy kT. Due to the minus sign in the denominator, at low energies an avalanche effect can occur—Bose–Einstein condensation: a macroscopic number of particles accumulates on the lowest energy level.

History

In 1924, Satyendra Nath Bose derived Planck's formula for thermal radiation by considering photons as indistinguishable quanta and using a new way of counting states (without the assumption of particle independence). The paper was rejected by European journals, and Bose turned to Albert Einstein. Einstein translated it into German and published it, and in 1924–1925 developed a general theory of an ideal Bose gas, predicting condensation at low temperatures. Experimental confirmation came 70 years later: in 1995, Eric Cornell and Carl Wieman cooled rubidium atoms to 170 nanokelvin and observed BEC, and Wolfgang Ketterle soon achieved a sodium condensate. All three received the Nobel Prize in 2001.

How it works

Bose–Einstein statistics underlies the superfluidity of helium-4, where boson atoms condense and flow without viscosity through microscopic capillaries. In superconductors, electrons, being fermions, bind into Cooper pairs—composite bosons—and obey Bose statistics, which leads to zero electrical resistance below a critical temperature. Lasers generate coherent light thanks to stimulated emission, the probability of which directly follows from the bosonic factor (n_i + 1). Limits of applicability: the gas must be sufficiently dilute and cold so that interactions do not distort the statistics; with strong interactions or in the non-ideal case, perturbation theory breaks down.

In practice

It underlies superconductivity, lasers, and frictionless liquid helium; without it, there would be no MRI and ultra-precise atomic clocks.

Fun fact

The boson is named after Bose himself, and the term was coined by Paul Dirac. The most famous boson is the photon, but a whole atom, such as rubidium-87, can also be a boson. It was on it that in 1995 the Bose–Einstein condensate—the 'fifth state of matter'—was first obtained.

Concept graph →

Formulas

$$\langle n \rangle = \frac{1}{e^{\hbar\omega / k_B T} - 1}$$
Average occupation number for bosonic energy states.
What is in the formula
\langle n \ranglevariableAverage occupation number — occupation number
\omegavariableAngular frequency of the bosonic mode — angular frequency radian per second
TvariableAbsolute temperature — temperature kelvin
\hbarconstantReduced Planck constant, relating energy to angular frequency. — reduced planck constant = 1.054571817e-34 joule second
k_BconstantBoltzmann constant, relating temperature to energy. — boltzmann constant = 1.380649e-23 joule per kelvin
\bar{n}=\frac{1}{e^{ħω/k_bt}-1} · 2606.25834

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