
Einstein's photoelectric equation describes how light quanta eject electrons from a material with kinetic energy dependent on frequency.Is light a stream of bullets, or waves? The photoelectric effect declared: bullets. Electrons are ejected from metal only if the light frequency exceeds a threshold, and the energy depends on the color, not the brightness. Einstein's equation E = hf — W precisely describes how much energy the electron retains after escape.
Albert Einstein, inspired by Max Planck's quantum hypothesis, introduced the concept of the photon and proposed the photoelectric equation in his March 1905 paper. Experimental confirmation was provided by Robert Millikan in 1916 after years of testing. Einstein received the Nobel Prize in Physics in 1921 precisely for this work.
The equation underlies photoemission spectroscopy, which allows measuring the work function of materials and surface chemical composition. Applicable for ultraviolet and visible radiation on metals; for the X-ray range relativistic corrections are required, and for semiconductors electron affinity is used instead of the work function.
Einstein received the 1921 Nobel Prize for explaining the photoelectric effect, not for the theory of relativity, which initially seemed too bold.
| E | variable | Energy of a photon — energy joule |
| f | variable | Frequency of the electromagnetic wave — frequency hertz |
| h | constant | Fundamental constant relating energy to frequency in quantum mechanics — planck constant = 6.62607015e-34 joule second |
| E | variable | Energy of a photon — energy joule |
| ν | variable | Frequency of the photon — frequency hertz |
| h | constant | Fundamental constant relating energy and frequency of a quantum — planck constant = 6.62607015e-34 joule second |
| y | variable | Source position on the sky — angular position radian |
| x | variable | Image position on the sky — angular position radian |
| α | variable | Deflection angle of light — deflection angle radian |
| E | variable | energy of the photon — energy joule |
| λ | variable | wavelength of the photon — wavelength metre |
| h | constant | fundamental constant relating energy to frequency — planck constant = 6.62607015e-34 joule second |
| c | constant | speed of light in vacuum — speed of light = 299792458 metre per second |



















