process

chemical reaction

A process that involves rearrangement of the molecular or ionic structure of a substance.
17 related articles

Description

A chemical reaction is a process in which substances (reactants) are transformed into new substances (products) through the breaking and forming of chemical bonds. This involves the rearrangement of atoms, ions, or molecules, but the total mass and number of atoms remain conserved. Chemical reactions are central to all of chemistry, from the combustion of fuels to the synthesis of pharmaceuticals, and they underpin biological processes like metabolism and photosynthesis. The study of reaction mechanisms—the step-by-step sequence of bond breaking and forming—is crucial for controlling and optimizing reactions.

History

The modern concept of a chemical reaction emerged in the late 18th century with Antoine Lavoisier's law of conservation of mass and his work on combustion. John Dalton's atomic theory (1803) provided the framework for understanding reactions as rearrangements of atoms, and later, the development of thermodynamics and kinetics in the 19th century refined the understanding of reaction energetics and rates.

How it works

During a chemical reaction, reactant molecules collide with sufficient energy and proper orientation to overcome the activation energy barrier. Bonds in the reactants break, and new bonds form in the products, often through intermediate species. The reaction rate depends on factors like temperature, concentration, and the presence of catalysts, which lower the activation energy without being consumed. The overall energy change (exothermic or endothermic) is determined by the difference between the bond energies of reactants and products.

In practice

Chemical reactions are used in virtually every industrial process, including the Haber process for ammonia synthesis, combustion engines, battery operation, and the production of plastics and medicines.

Fun fact

Some chemical reactions, like the Belousov-Zhabotinsky reaction, exhibit oscillating color changes over time, demonstrating that reactions can be far from equilibrium and show complex, wave-like behavior.

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Related articles · 17

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A Recipe for a Cell: Why Chemistry Can't Be Programmed in a Hurry
A cookbook without a shopping list: that's what a scientist faces when looking at a scheme of chemical reactions. The arrows and formulas on paper look neat, but once you start hunting in the lab for molecules that will actually behave that way, a real quest begins.
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Chemistry Under the Metronome
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AI Masters the Cookbook of Chemical Reactions
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Gold Dust at the Edge of Worlds
Gold on carbon is a classic pairing in chemistry. Such materials speed up important reactions, like producing vinyl chloride for plastics. But until now, no one had seen in detail how gold atoms behave on a graphite surface when the whole thing is immersed in a liquid.
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Chemistry Without Hints: Reconstructing Reaction Mechanisms from Data
When chemists see how concentrations of substances change, they need to figure out which reactions are behind those changes. It's like trying to reconstruct a recipe from photos of plates at different stages of a meal. Previously, this often involved derivatives — instantaneous rates of concentration change.
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Light Changes the Speed of Chemistry
An ordinary chemical reaction is like a ball rolling down a hill: it has one natural path. But if you place molecules in a tiny mirrored box, an optical microresonator, the light inside starts to interfere with the ball's motion. It can nudge it, hold it back, or even split its trajectory. In a new study, physicists traced exactly how this happens.
Galaxies2026-01-092 minarXiv:2601.05757express
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