concept

catalysis

Catalysis is a process that accelerates chemical reactions without being consumed, often involving metal atoms or plasma.
14 related articles

Description

Catalysis is the increase in the rate of a chemical reaction under the action of a substance that is not part of the final products. The catalyst lowers the activation energy (energy barrier), opening an alternative reaction pathway. It can be homogeneous (in the same phase as the reactants) or heterogeneous (usually a solid in a liquid or gaseous medium).

History

The term 'catalysis' was introduced by Swedish chemist Jöns Jacob Berzelius in 1836 to describe reactions accelerated in the presence of substances that themselves do not change. In 1895, Wilhelm Ostwald gave a quantitative definition of a catalyst as a substance that accelerates a reaction but does not shift equilibrium. In the early 20th century, Paul Sabatier discovered hydrogenation on metallic nickel, for which he received the Nobel Prize. Fritz Haber and Carl Bosch developed catalytic synthesis of ammonia, revolutionizing agriculture. Further development of enzymatic catalysis is associated with the names of Michaelis, Menten, Briggs and Haldane. Today, catalysis permeates petrochemistry, energy, and environmental protection.

How it works

The catalyst provides an alternative reaction pathway with a lower activation energy. In heterogeneous catalysis, chemisorption plays a decisive role — the formation of chemical bonds between the reactants and the active sites on the surface. This weakens certain interatomic bonds in the reactant molecules, facilitating their breaking. Then the adsorbed particles interact, forming products that desorb, freeing the sites. For example, in ammonia synthesis on an iron catalyst, N₂ and H₂ molecules dissociate into atoms, which requires high energy without a catalyst. The reaction rate is often described by the Arrhenius equation: k = A exp(-Ea/RT), where Ea is the activation energy. The catalyst lowers Ea. In enzymes, an additional role is played by the complementarity of the active site to the substrate (lock-and-key model) and stabilization of the transition state.

In practice

Catalytic converters in cars transform toxic exhaust gases into safe nitrogen and water.

Fun fact

The same catalyst can accelerate both the forward and reverse reactions — it does not shift the equilibrium, only helps to reach it faster.

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Related articles · 18

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