Measures ultrafast dynamics by exciting with pump pulse and probing with delayed pulse.Pump-probe spectroscopy is a technique for observing events that happen on timescales of femtoseconds (10^-15 s) to picoseconds (10^-12 s), far faster than any electronic detector can directly record. It works by using two laser pulses: a 'pump' pulse initiates a process in a sample, and a 'probe' pulse, arriving after a precisely controlled delay, measures the state of the sample at that moment. By repeating the experiment with different delays, scientists can reconstruct a movie of the ultrafast dynamics.
The technique was pioneered in the 1970s and 1980s, with key contributions from researchers like Peter Rentzepis and Ahmed Zewail, who used it to study chemical reactions in real time.
The pump pulse excites the sample, creating a non-equilibrium state. The probe pulse, which is usually weaker and often at a different wavelength, interacts with the sample and is then measured. The delay between the two pulses is controlled by changing the optical path length of the probe beam (e.g., with a movable mirror), since light travels about 0.3 micrometers per femtosecond. The measured probe signal (e.g., transmission, reflection, or induced fluorescence) is recorded as a function of delay, building up a time-resolved trace of the system's evolution.
It is used to study photosynthesis, charge transfer in solar cells, and the dynamics of phonons and electrons in semiconductors, as well as to characterize the properties of novel materials.
The fastest pump-probe experiments can resolve events that last only a few attoseconds (10^-18 s), using isolated attosecond pulses rather than femtosecond ones.








