
Bloch's theorem describes electron wavefunctions in periodic crystals as modulated plane waves.In 1928, Felix Bloch, working on his dissertation under Heisenberg, pondered: how to describe an electron in a crystal where the atoms are arranged periodically? The answer turned out to be surprisingly elegant: the wave function must be 'Bloch-like' — the product of a plane wave and a function repeating with the lattice spacing. This naturally led to the idea of energy bands: some energy intervals are allowed, others forbidden. Thus band theory was born, explaining the difference between metals, dielectrics, and semiconductors.
In 1928, Felix Bloch, completing his dissertation under Werner Heisenberg in Leipzig, rigorously proved that the electron wave function in a periodic potential must have the specified form. This immediately led to an understanding of the band nature of the spectrum and became the key to the theory of metals and insulators. Later the theorem was generalized to the case of an external magnetic field (Rama-Showen theorem), as well as to systems with strong spin-orbit coupling and topological phases.
The theorem is strictly valid only for ideal infinite crystals. Impurities, boundaries, defects, and thermal vibrations break translational symmetry, and Bloch states cease to be proper. Nevertheless, for most real materials, the Bloch approximation works excellently. To account for electron-electron correlations, one must go beyond the single-electron picture; modern methods include density functional theory and dynamical mean field theory.
The entire band theory of solids rests on Bloch's theorem. Without it, it is impossible to understand why some materials conduct electricity and others do not, and to design a transistor, LED, or laser.
Bloch left his mark in various fields: there are 'Bloch walls' in magnetism and the 'Bloch sphere' for qubits, but his theorem on waves in a crystal is a separate masterpiece.
| \theta | variable | Polar angle on the Bloch sphere — polar angle radian |
| \phi | variable | Azimuthal angle on the Bloch sphere — azimuthal angle radian |
| |\theta,\phi\rangle | variable | Quantum state on the Bloch sphere — quantum state |
| |0\rangle | variable | Computational basis state 0 — basis state |
| |1\rangle | variable | Computational basis state 1 — basis state |
| E | variable | Kinetic energy of the charged particle — energy joule |
| x | variable | Path length in the material — length metre |
| \rho | variable | Density of the absorbing material — density kilogram per cubic metre |
| z | variable | Charge number of the incident particle — charge number |
| A | variable | Atomic mass number of the absorber — atomic mass number |
| \beta | variable | Speed of the particle relative to the speed of light — velocity ratio |
| \gamma | variable | Lorentz factor of the particle — lorentz factor |
| v | variable | Speed of the particle — velocity metre per second |
| W_{\text{max}} | variable | Maximum energy transfer in a single collision — energy joule |
| I | variable | Mean excitation potential of the absorber — energy joule |
| \delta | variable | Density correction factor — density correction |
| C | variable | Shell correction factor — shell correction |
| Z | variable | Atomic number of the absorber — atomic number |
| N_A | constant | Number of constituent particles per mole — avogadro constant = 6.02214076e23 per mole |
| r_e | constant | Radius of a classical electron — classical electron radius = 2.8179403262e-15 metre |
| m_e | constant | Rest mass of the electron — electron mass = 9.1093837015e-31 kilogram |
| c | constant | Speed of light in vacuum — speed of light = 299792458 metre per second |
| -\frac{d}{dx} | operator | Negative derivative with respect to path length — negative derivative |
| \ln | operator | Natural logarithm — natural logarithm |
| \lambda | variable | de Broglie wavelength of the particle — wavelength metre |
| p | variable | momentum of the particle — momentum kilogram metre per second |
| h | constant | Planck constant, the quantum of action — planck constant = 6.62607015e-34 joule second |
| θ | variable | Polar angle on Bloch sphere — angle radian |
| φ | variable | Azimuthal angle on Bloch sphere — angle radian |
| |θ,φ⟩ | variable | Qubit state vector — quantum state |
| ψ | variable | wave function — wave function |
| x | variable | position coordinate — position metre |
| V(x) | variable | potential energy function — potential energy joule |
| E | variable | energy eigenvalue — energy joule |
| d²/dx² | operator | second derivative with respect to position — second derivative |




















