theorem

Bloch's theorem

Bloch's theorem describes electron wavefunctions in periodic crystals as modulated plane waves.
14 related articles · 5 formulas · 1 who worked here

Description

In 1928, Felix Bloch, working on his dissertation under Heisenberg, pondered: how to describe an electron in a crystal where the atoms are arranged periodically? The answer turned out to be surprisingly elegant: the wave function must be 'Bloch-like' — the product of a plane wave and a function repeating with the lattice spacing. This naturally led to the idea of energy bands: some energy intervals are allowed, others forbidden. Thus band theory was born, explaining the difference between metals, dielectrics, and semiconductors.

History

In 1928, Felix Bloch, completing his dissertation under Werner Heisenberg in Leipzig, rigorously proved that the electron wave function in a periodic potential must have the specified form. This immediately led to an understanding of the band nature of the spectrum and became the key to the theory of metals and insulators. Later the theorem was generalized to the case of an external magnetic field (Rama-Showen theorem), as well as to systems with strong spin-orbit coupling and topological phases.

How it works

The theorem is strictly valid only for ideal infinite crystals. Impurities, boundaries, defects, and thermal vibrations break translational symmetry, and Bloch states cease to be proper. Nevertheless, for most real materials, the Bloch approximation works excellently. To account for electron-electron correlations, one must go beyond the single-electron picture; modern methods include density functional theory and dynamical mean field theory.

In practice

The entire band theory of solids rests on Bloch's theorem. Without it, it is impossible to understand why some materials conduct electricity and others do not, and to design a transistor, LED, or laser.

Fun fact

Bloch left his mark in various fields: there are 'Bloch walls' in magnetism and the 'Bloch sphere' for qubits, but his theorem on waves in a crystal is a separate masterpiece.

Concept graph →

Formulas

$$| heta,\phi\rangle = \cos(\theta/2)\,|0\rangle + e^{i\phi}\sin(\theta/2)\,|1\rangle$$
Quantum state on Bloch sphere with polar and azimuthal angles.
What is in the formula
\thetavariablePolar angle on the Bloch sphere — polar angle radian
\phivariableAzimuthal angle on the Bloch sphere — azimuthal angle radian
|\theta,\phi\ranglevariableQuantum state on the Bloch sphere — quantum state
|0\ranglevariableComputational basis state 0 — basis state
|1\ranglevariableComputational basis state 1 — basis state
|\psi(0)\rangle=\cos(α/2)|r,0\rangle+e^{iβ}\sin(α/2)|l,0\rangle · 2505.01532v1
$$-\frac{dE}{dx} = \frac{4\pi N_A r_e^2 m_e c^2 \rho z^2}{A \beta^2} \left[ \ln\left(\frac{2m_e \gamma^2 v^2 W_{\text{max}}}{I^2}\right) - 2\beta^2 - \delta - 2\frac{C}{Z} \right]$$
Energy loss of charged particles due to ionization in matter.
What is in the formula
EvariableKinetic energy of the charged particle — energy joule
xvariablePath length in the material — length metre
\rhovariableDensity of the absorbing material — density kilogram per cubic metre
zvariableCharge number of the incident particle — charge number
AvariableAtomic mass number of the absorber — atomic mass number
\betavariableSpeed of the particle relative to the speed of light — velocity ratio
\gammavariableLorentz factor of the particle — lorentz factor
vvariableSpeed of the particle — velocity metre per second
W_{\text{max}}variableMaximum energy transfer in a single collision — energy joule
IvariableMean excitation potential of the absorber — energy joule
\deltavariableDensity correction factor — density correction
CvariableShell correction factor — shell correction
ZvariableAtomic number of the absorber — atomic number
N_AconstantNumber of constituent particles per mole — avogadro constant = 6.02214076e23 per mole
r_econstantRadius of a classical electron — classical electron radius = 2.8179403262e-15 metre
m_econstantRest mass of the electron — electron mass = 9.1093837015e-31 kilogram
cconstantSpeed of light in vacuum — speed of light = 299792458 metre per second
-\frac{d}{dx}operatorNegative derivative with respect to path length — negative derivative
\lnoperatorNatural logarithm — natural logarithm
-\langle\frac{de}{dx}\rangle=2πn_ar_e^2c^2ρ\frac{z}{a}\frac{z^2}{β^2}[\ln(\frac{2m_eγ^2v^2w_{\max}}{i^2})-2β^2-δ-2\frac{c}{z}] · 2607.27531v1
$$\lambda = \frac{h}{p}$$
Wavelength of a particle equals Planck's constant divided by momentum.
What is in the formula
\lambdavariablede Broglie wavelength of the particle — wavelength metre
pvariablemomentum of the particle — momentum kilogram metre per second
hconstantPlanck constant, the quantum of action — planck constant = 6.62607015e-34 joule second
λ=\frac{h}{p} · 2607.03465
\langle|{q}|^2\rangle\propto(n_e/ν) · 2607.08822
λ=\frac{h}{p}=\frac{h}{\sqrt{2me}} · 2607.10388
λ=\frac{h}{m_gc} · 2607.11764
$$|\theta, \phi\rangle = \begin{pmatrix} \cos\frac{\theta}{2} e^{-i\frac{\phi}{2}} \\ \sin\frac{\theta}{2} e^{i\frac{\phi}{2}} \end{pmatrix}$$
A qubit's pure state parameterized by polar and azimuthal angles on the Bloch sphere.
What is in the formula
θvariablePolar angle on Bloch sphere — angle radian
φvariableAzimuthal angle on Bloch sphere — angle radian
|θ,φ⟩variableQubit state vector — quantum state
|θ,φ\rangle=\begin{pmatrix}\cos\frac{θ}{2}e^{-i\frac{φ}{2}}\\sin\frac{θ}{2}e^{i\frac{φ}{2}}\end{pmatrix} · 2505.00777v1
$$-\frac{d^2 \psi}{dx^2} + V(x) \psi = E \psi$$
A wave function's evolution in a potential is governed by the Schrödinger equation.
What is in the formula
ψvariablewave function — wave function
xvariableposition coordinate — position metre
V(x)variablepotential energy function — potential energy joule
Evariableenergy eigenvalue — energy joule
d²/dx²operatorsecond derivative with respect to position — second derivative
-\frac{d^2h}{d\eta_*^2}+v(\eta_*)h=ε^2ω^2h · 2605.11565v1
\hat{h}ψ=eψ · 2606.22926
iħ\frac{\partialψ}{\partialt}=(-\frac{ħ^2}{2m}\frac{\partial^2}{\partialx^2}+v(x)-iw(x))ψ · 2607.03845
iħ\frac{\partialψ}{\partialt}=-\frac{ħ^2}{2m}\nabla^2ψ+m\phiψ · 2607.16917v1

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